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Apatite formation on a hydrogel containing sulfinic acid group under physiological conditions
http://hdl.handle.net/10228/00006934
http://hdl.handle.net/10228/0000693469967bea-a3fc-4696-81b1-03579f2a9636
名前 / ファイル | ライセンス | アクション |
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jbmrbab_105_7.pdf (2.1 MB)
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Item type | 学術雑誌論文 = Journal Article(1) | |||||||||||||||||
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公開日 | 2018-10-01 | |||||||||||||||||
資源タイプ | ||||||||||||||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||||||||
資源タイプ | journal article | |||||||||||||||||
タイトル | ||||||||||||||||||
タイトル | Apatite formation on a hydrogel containing sulfinic acid group under physiological conditions | |||||||||||||||||
言語 | ||||||||||||||||||
言語 | eng | |||||||||||||||||
著者 |
Hamai, Ryo
× Hamai, Ryo× 城崎, 由紀
WEKO
15664
× 宮崎, 敏樹
WEKO
6369
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抄録 | ||||||||||||||||||
内容記述タイプ | Abstract | |||||||||||||||||
内容記述 | Natural bone consists of apatite and collagen fiber. Bioactive materials capable to bonding to bone tissue are clinically used as bone-repairing materials. Apatite-organic polymer composites exhibit bone-bonding abilities and mechanical properties similar to those of natural bone, and these materials can be prepared using biomimetic processes in simulated body fluid (SBF). Specific functional groups such as sulfonic and carboxylic acid groups are known to induce the heterogeneous nucleation of apatite in SBF. However, it remains unclear whether structurally related sulfinic acid groups can contribute to apatite formation in the same way, despite sodium sulfonate being used in biomedical applications as a radical polymerization promoter in adhesive dental resin. Herein, we report the preparation of a new hydrogel containing sulfinic acid groups from sodium 4-vinylbenzenesulfinate and 2-hydroxyethyl methacrylate using a radical polymerization reaction and the subsequent incorporation of Ca2+ ions into this material. We also investigated the apatite-forming behavior of these hydrogels in SBF. Hydrogels containing sulfinic acid groups showed higher apatite-forming ability than those without sulfinic acid groups. In addition, the apatite layer formed on the former showed tight adhesion to the hydrogel. This phenomenon was attributed to the heterogeneous nucleation of apatite, induced by the sulfinic acid groups. | |||||||||||||||||
書誌情報 |
Journal of biomedical materials research. Part B, Applied biomaterials 巻 105, 号 7, p. 1924-1929, 発行日 2017-10-01 |
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出版社 | ||||||||||||||||||
出版者 | John Wiley & Sons, Inc. | |||||||||||||||||
DOI | ||||||||||||||||||
関連タイプ | isVersionOf | |||||||||||||||||
識別子タイプ | DOI | |||||||||||||||||
関連識別子 | https://doi.org/10.1002/jbm.b.33732 | |||||||||||||||||
NCID | ||||||||||||||||||
収録物識別子タイプ | NCID | |||||||||||||||||
収録物識別子 | AA12001425 | |||||||||||||||||
ISSN | ||||||||||||||||||
収録物識別子タイプ | ISSN | |||||||||||||||||
収録物識別子 | 1552-4981 | |||||||||||||||||
著作権関連情報 | ||||||||||||||||||
権利情報 | Copyright (c) 2016 Wiley Periodicals, Inc. | |||||||||||||||||
キーワード | ||||||||||||||||||
主題Scheme | Other | |||||||||||||||||
主題 | composite/hard tissue | |||||||||||||||||
キーワード | ||||||||||||||||||
主題Scheme | Other | |||||||||||||||||
主題 | calcium phosphate(s) | |||||||||||||||||
キーワード | ||||||||||||||||||
主題Scheme | Other | |||||||||||||||||
主題 | hydrogel | |||||||||||||||||
キーワード | ||||||||||||||||||
主題Scheme | Other | |||||||||||||||||
主題 | sulfinic acid group | |||||||||||||||||
キーワード | ||||||||||||||||||
主題Scheme | Other | |||||||||||||||||
主題 | bone graft | |||||||||||||||||
出版タイプ | ||||||||||||||||||
出版タイプ | AM | |||||||||||||||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||||||||||||||
査読の有無 | ||||||||||||||||||
値 | yes | |||||||||||||||||
研究者情報 | ||||||||||||||||||
https://hyokadb02.jimu.kyutech.ac.jp/html/323_ja.html | ||||||||||||||||||
論文ID(連携) | ||||||||||||||||||
10308737 | ||||||||||||||||||
連携ID | ||||||||||||||||||
6323 |