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Enhanced Crystallization by Methanol Additive in Antisolvent for Achieving High‐Quality MAPbI3 Perovskite Films in Humid Atmosphere
http://hdl.handle.net/10228/00007125
http://hdl.handle.net/10228/0000712528a232d1-6d8e-46f9-b1a6-6a10ea1a2b52
名前 / ファイル | ライセンス | アクション |
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cssc.201800625.pdf (2.2 MB)
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Item type | 学術雑誌論文 = Journal Article(1) | |||||||||||
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公開日 | 2019-05-07 | |||||||||||
資源タイプ | ||||||||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||
資源タイプ | journal article | |||||||||||
タイトル | ||||||||||||
タイトル | Enhanced Crystallization by Methanol Additive in Antisolvent for Achieving High‐Quality MAPbI3 Perovskite Films in Humid Atmosphere | |||||||||||
言語 | ||||||||||||
言語 | eng | |||||||||||
著者 |
Yang, Fu
× Yang, Fu× Kamarudin, Muhammad Akmal× Zhang, Putao× Kapil, Gaurav× 馬, 廷麗
WEKO
21419
× 早瀬, 修二 |
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抄録 | ||||||||||||
内容記述タイプ | Abstract | |||||||||||
内容記述 | Perovskite solar cells have attracted considerable attention owing to their easy and low‐cost solution manufacturing process with high power conversion efficiency. However, the fabrication process is usually performed inside a glovebox to avoid moisture, as organometallic halide perovskites are easily dissolved in water. In this study, we propose a one‐step fabrication of high‐quality MAPbI3 perovskite films in around 50% relative humidity (RH) humid ambient air by using diethyl ether as an antisolvent and methanol as an additive into this antisolvent. Because of the presence of methanol, the water molecules can be efficiently removed from the gaps of the perovskite precursors and the perovskite film formation can be slightly controlled, leading to pinhole‐free and low roughness films. Concurrently, methanol can be used to tune the DMSO ratio in the intermediate perovskite phase to regulate perovskite formation. Planar solar cells fabricated by using this method exhibited the best efficiency of 16.4% with a reduced current density–voltage hysteresis. This efficiency value is approximately 160% higher than the devices fabrication by using only diethyl ether treatment. From the impedance measurement, it is also found that the recombination reaction is suppressed when the device is prepared with methanol additive in the antisolvent. This method presents a new path for controlling the growth and morphology of perovskite films in humid climates and laboratories with uncontrolled environments. | |||||||||||
書誌情報 |
ChemSusChem 巻 11, 号 14, p. 2348-2357, 発行日 2018-05-04 |
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出版社 | ||||||||||||
出版者 | Wiley-V C H Verlag GMBH | |||||||||||
DOI | ||||||||||||
関連タイプ | isVersionOf | |||||||||||
識別子タイプ | DOI | |||||||||||
関連識別子 | https://doi.org/10.1002/cssc.201800625 | |||||||||||
日本十進分類法 | ||||||||||||
主題Scheme | NDC | |||||||||||
主題 | 543 | |||||||||||
NCID | ||||||||||||
収録物識別子タイプ | NCID | |||||||||||
収録物識別子 | AA12309282 | |||||||||||
ISSN | ||||||||||||
収録物識別子タイプ | ISSN | |||||||||||
収録物識別子 | 1864-5631 | |||||||||||
ISSN | ||||||||||||
収録物識別子タイプ | ISSN | |||||||||||
収録物識別子 | 1864-564X | |||||||||||
著作権関連情報 | ||||||||||||
権利情報 | Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim | |||||||||||
キーワード | ||||||||||||
主題Scheme | Other | |||||||||||
主題 | antisolvent | |||||||||||
キーワード | ||||||||||||
主題Scheme | Other | |||||||||||
主題 | humid atmosphere | |||||||||||
キーワード | ||||||||||||
主題Scheme | Other | |||||||||||
主題 | methanol additive | |||||||||||
キーワード | ||||||||||||
主題Scheme | Other | |||||||||||
主題 | perovskites | |||||||||||
キーワード | ||||||||||||
主題Scheme | Other | |||||||||||
主題 | planar solar cells | |||||||||||
出版タイプ | ||||||||||||
出版タイプ | AM | |||||||||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||||||||
査読の有無 | ||||||||||||
値 | yes | |||||||||||
連携ID | ||||||||||||
7516 | ||||||||||||
資料タイプ | ||||||||||||
内容記述タイプ | Other | |||||||||||
内容記述 | Journal Article | |||||||||||
著者所属 | ||||||||||||
Graduate School of Life Science and Systems Engineering Institution, Kyushu Institute of Technology, Kitakyushu, 808-0196 Japan | ||||||||||||
著者所属 | ||||||||||||
Graduate School of Life Science and Systems Engineering Institution, Kyushu Institute of Technology, Kitakyushu, 808-0196 Japan | ||||||||||||
著者所属 | ||||||||||||
Graduate School of Life Science and Systems Engineering Institution, Kyushu Institute of Technology, Kitakyushu, 808-0196 Japan | ||||||||||||
著者所属 | ||||||||||||
Graduate School of Life Science and Systems Engineering Institution, Kyushu Institute of Technology, Kitakyushu, 808-0196 Japan | ||||||||||||
著者所属 | ||||||||||||
Graduate School of Life Science and Systems Engineering Institution, Kyushu Institute of Technology, Kitakyushu, 808-0196 Japan | ||||||||||||
著者所属 | ||||||||||||
Graduate School of Life Science and Systems Engineering Institution, Kyushu Institute of Technology, Kitakyushu, 808-0196 Japan |