Kyushu Institute of Technology Academic Repository
Kyutacarは九州工業大学で生産された研究成果を オープンアクセスで提供する機関リポジトリシステムです。 Kyutacar is open-access repository of research by members of the Kyushu Institute of Technology.
Single crystal X-ray structural analysis, Ce valence evaluation, Resistivity under high pressure, BiS2-based superconductors, Layered mixed-anion compounds
WPI-MANA, National Institute for Materials Science, Tsukuba, Ibaraki 305-0047, Japan, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8577, Japan
WPI-MANA, National Institute for Materials Science, Tsukuba, Ibaraki 305-0047, Japan, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8577, Japan
WPI-MANA, National Institute for Materials Science, Tsukuba, Ibaraki 305-0047, Japan, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8577, Japan
WPI-MANA, National Institute for Materials Science, Tsukuba, Ibaraki 305-0047, Japan, Graduate School of Engineering, Kyushu Institute of Technology, Kitakyushu 804-8550, Japan
WPI-MANA, National Institute for Materials Science, Tsukuba, Ibaraki 305-0047, Japan, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8577, Japan
National Institute of Technology, Yonago College, Yonago, Tottori 683-8502, Japan
WPI-MANA, National Institute for Materials Science, Tsukuba, Ibaraki 305-0047, Japan
National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8568, Japan
WPI-MANA, National Institute for Materials Science, Tsukuba, Ibaraki 305-0047, Japan, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8577, Japan
抄録
We found that the electronic transport property of SnSe single crystals was sensitively affected by oxidation in raw Sn. Semiconducting SnSe single crystals were obtained by using Sn of grain form as a starting material while powder Sn resulted in metallic SnSe. X-ray photoelectron spectroscopy analysis revealed that the surfaces of raw Sn were oxidized, which volume fraction is lower in grain Sn. This indicates that the amount of oxygen in raw Sn is the key factor for the electronic transport property of SnSe.