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Fabrication of morphology-controlled TiO2 photocatalyst nanoparticles and improvement of photocatalytic activities by modification of Fe compounds
http://hdl.handle.net/10228/00006501
http://hdl.handle.net/10228/00006501e44ce796-fc17-429f-b37d-755ba16352fa
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RM34_291.pdf (650.4 kB)
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Item type | 学術雑誌論文 = Journal Article(1) | |||||||||||
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公開日 | 2018-01-11 | |||||||||||
資源タイプ | ||||||||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||
資源タイプ | journal article | |||||||||||
タイトル | ||||||||||||
タイトル | Fabrication of morphology-controlled TiO2 photocatalyst nanoparticles and improvement of photocatalytic activities by modification of Fe compounds | |||||||||||
言語 | ||||||||||||
言語 | eng | |||||||||||
著者 |
横野, 照尚
× 横野, 照尚
WEKO
6794
× Lee, Szu Ying× Yang, Yin |
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抄録 | ||||||||||||
内容記述タイプ | Abstract | |||||||||||
内容記述 | Our previous studies suggested that redox reaction proceeded separately on specific exposed crystal faces of TiO2 nanoparticles. Site-selective deposition of metal or metal oxide on TiO2 specific exposed crystal faces successfully proceeded using the unique reactivity properties on the surface of TiO2 nanoparticles under photoexcitation. A remarkable improvement of photocatalytic activity of shape-controlled brookite and rutile TiO2 nanorods with modification of Fe3+ compounds was observed under visible light. Crystal face-selective metal compound modification on exposed crystal faces of TiO2 nanorods with brookite and rutile phases was successfully prepared. Brookite and rutile TiO2 nanorods prepared by site-selective modification with metal compounds should be ideal visible-light responsive TiO2 photocatalysts because of the remarkable suppression of back electron transfer from TiO2 to oxidized metal compounds on the surface of the TiO2 nanorod with a brookite or rutile phase. In this paper, the development of exposed crystal face-controlled TiO2 nanorods with rutile and brookite phases was described. The obtained rutile and brookite TiO2 nanorod, showing remarkably high activity for degradation of organic compounds compared with the photocatalytic activities of anatase fine particles (ST-01), is one of the most active commercially available photocatalysts for environmental cleanup in Japan. The technology of visible-light responsive treatment for morphology-controlled rutile and brookite TiO2 nanorods by crystal face-selective modification of Fe3+ compounds was also discussed in this paper. The Fe3+ compound-modified rutile and brookite TiO2 nanorods show much higher activity than conventional visible-light responsive N-doped TiO2, which is commercially available in Japan. | |||||||||||
書誌情報 |
Rare metals 巻 34, 号 5, p. 291-300, 発行日 2015-05 |
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出版社 | ||||||||||||
出版者 | Springer Verlag | |||||||||||
DOI | ||||||||||||
関連タイプ | isVersionOf | |||||||||||
識別子タイプ | DOI | |||||||||||
関連識別子 | https://doi.org/10.1007/s12598-015-0483-8 | |||||||||||
NCID | ||||||||||||
収録物識別子タイプ | NCID | |||||||||||
収録物識別子 | AA11855662 | |||||||||||
ISSN | ||||||||||||
収録物識別子タイプ | ISSN | |||||||||||
収録物識別子 | 1001-0521 | |||||||||||
ISSN | ||||||||||||
収録物識別子タイプ | ISSN | |||||||||||
収録物識別子 | 1867-7185 | |||||||||||
著作権関連情報 | ||||||||||||
権利情報 | The Nonferrous Metals Society of China and Springer-Verlag Berlin Heidelberg 2015 | |||||||||||
著作権関連情報 | ||||||||||||
権利情報 | The final publication is available at Springer via http://dx.doi.org/10.1007/s12598-015-0483-8 | |||||||||||
キーワード | ||||||||||||
主題Scheme | Other | |||||||||||
主題 | Morphology-controlled TiO2 | |||||||||||
キーワード | ||||||||||||
主題Scheme | Other | |||||||||||
主題 | Separation of reaction sites | |||||||||||
キーワード | ||||||||||||
主題Scheme | Other | |||||||||||
主題 | Visible-light responsive TiO2 loaded with Fe3+ | |||||||||||
出版タイプ | ||||||||||||
出版タイプ | AM | |||||||||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||||||||
査読の有無 | ||||||||||||
値 | yes | |||||||||||
研究者情報 | ||||||||||||
表示名 | https://hyokadb02.jimu.kyutech.ac.jp/html/98_ja.html | |||||||||||
URL | https://hyokadb02.jimu.kyutech.ac.jp/html/98_ja.html | |||||||||||
論文ID(連携) | ||||||||||||
値 | 10292239 | |||||||||||
連携ID | ||||||||||||
値 | 6506 |