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Photovoltaic Properties of CdSe Quantum Dot Sensitized Inverse Opal TiO2 Solar Cells: The Effect of TiCl4 Post Treatment
http://hdl.handle.net/10228/00006572
http://hdl.handle.net/10228/00006572ded02ed7-0688-4783-913d-42e318085c68
名前 / ファイル | ライセンス | アクション |
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JMP8_522.pdf (1.1 MB)
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Item type | 学術雑誌論文 = Journal Article(1) | |||||
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公開日 | 2018-02-20 | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
タイトル | ||||||
タイトル | Photovoltaic Properties of CdSe Quantum Dot Sensitized Inverse Opal TiO2 Solar Cells: The Effect of TiCl4 Post Treatment | |||||
言語 | ||||||
言語 | eng | |||||
著者 |
Hironaka, Motoki
× Hironaka, Motoki× Toyoda, Taro× Hori, Kanae× Ogomi, Yuhei× 早瀬, 修二× Sheng, Qing |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Recently, semiconductor quantum dot (QD) sensitized solar cells (QDSSCs) are expected to achieve higher conversion efficiency because of the large light absorption coefficient and multiple exciton generation in QDs. The morphology of TiO2 electrode is one of the most important factors in QDSSCs. Inverse opal (IO) TiO2 electrode, which has periodic mesoporous structure, is useful for QDSSCs because of better penetration of electrolyte than conventional nanoparticulate TiO2 electrode. In addition, the ordered three dimensional structure of IO-TiO2 would be better for electron transport. We have found that open circuit voltage Voc of QDSSCs with IO-TiO2 electrodes was much higher (0.2 V) than that with nanoparticulate TiO2 electrodes. But short circuit current density Jsc was lower in the case of IO-TiO2 electrodes because of the smaller surface area of IO-TiO2. In this study, for increasing surface area of IO-TiO2, we applied TiCl4 post treatment on IO-TiO2 and investigated the effect of the post treatment on photovoltaic properties of CdSe QD sensitized IO-TiO2 solar cells. It was found that Jsc could be enhanced due to TiCl4 post treatment, but decreased again for more than one cycle treatment, which indicates excess post treatment may lead to worse penetration of electrolyte. Our results indicate that the appropriate post treatment can improve the energy conversion efficiency of the QDSSCs. | |||||
書誌情報 |
Journal of Modern Physics 巻 8, 号 4, p. 522-530, 発行日 2017-03-17 |
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出版社 | ||||||
出版者 | Scientific Research Publishing | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.4236/jmp.2017.84034 | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 2153-1196 | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 2153-120X | |||||
著作権関連情報 | ||||||
権利情報 | Copyright (c) 2017 by authors and Scientific Research Publishing Inc. | |||||
著作権関連情報 | ||||||
権利情報 | Creative Commons Attribution International License (CC BY 4.0). | |||||
著作権関連情報 | ||||||
権利情報 | http://creativecommons.org/licenses/by/4.0/ | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Quantum Dot Sensitized Solar Cells | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Inverse Opal Structure | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | TiCl4 Post Treatment | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Morphology of the TiO2 Electrode | |||||
出版タイプ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
査読の有無 | ||||||
値 | yes | |||||
研究者情報 | ||||||
https://hyokadb02.jimu.kyutech.ac.jp/html/322_ja.html | ||||||
論文ID(連携) | ||||||
10310148 | ||||||
連携ID | ||||||
6672 | ||||||
資料タイプ | ||||||
内容記述タイプ | Other | |||||
内容記述 | Journal Article | |||||
著者所属 | ||||||
Department of Engineering Science, The University of Electro-Communications | ||||||
著者所属 | ||||||
Department of Engineering Science, The University of Electro-Communications | ||||||
著者所属 | ||||||
Department of Engineering Science, The University of Electro-Communications | ||||||
著者所属 | ||||||
Graduate School of Life Science and Systems Engineering, Kyushu Institute of Technology | ||||||
著者所属 | ||||||
Graduate School of Life Science and Systems Engineering, Kyushu Institute of Technology | ||||||
著者所属 | ||||||
Department of Engineering Science, The University of Electro-Communications |