WEKO3
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Crystal structure of high-density Fe56 cluster Nd2Fe14B under high pressure
http://hdl.handle.net/10228/00008561
http://hdl.handle.net/10228/000085613bd5cc42-97a7-4249-8fc1-348b21e3e616
名前 / ファイル | ライセンス | アクション |
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10349788.pdf (615.5 kB)
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Item type | 学術雑誌論文 = Journal Article(1) | |||||||||||
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公開日 | 2021-11-22 | |||||||||||
資源タイプ | ||||||||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||
資源タイプ | journal article | |||||||||||
タイトル | ||||||||||||
タイトル | Crystal structure of high-density Fe56 cluster Nd2Fe14B under high pressure | |||||||||||
その他のタイトル | ||||||||||||
その他のタイトル | Crystal structure of high–density Fe56 cluster Nd2Fe14B under high pressure | |||||||||||
言語 | ||||||||||||
言語 | eng | |||||||||||
著者 |
Tajiri, Takayuki
× Tajiri, Takayuki× 美藤, 正樹
WEKO
1968
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抄録 | ||||||||||||
内容記述タイプ | Abstract | |||||||||||
内容記述 | Nd2Fe14B is a high-density Fe cluster containing 56 Fe atoms in one unit cell. We investigated the crystallographic structure of an isotropic Nd2Fe14B magnet comprising nanocrystals of a size of ~30 nm at pressures up to 2 GPa. The results of X-ray diffraction measurements using Rietveld refinement revealed the displacements of each Fe atomic site in the Fe cluster, Nd, and B atomic sites. The lattice constants, a and c, of tetragonal symmetry decreased proportionally with external pressure, whereas the shrinkage ratio for both a and c changed at approximately 0.5 GPa. However, each atomic position exhibited non-monotonic pressure dependence. The trend of displacement of atomic positions changed at a characteristic pressure of 0.4 ± 0.1 GPa. When exceeded, most atoms shifted to the direction opposite their displacement at lower pressures. Thus, they exhibited restoration tendencies toward the positions at ambient pressure. The bond angles and bond lengths among Nd, Fe, and B atoms also exhibited characteristic pressure dependences. As pressure increased, the basal triangle of the trigonal prism in the Fe cluster layers distorted up to ~0.5 GPa, whereas the strain of the trigonal prism gradually reduced just above 0.5 GPa. The atomic position of the heaviest Nd atoms was a key structural parameter to characterize the change. | |||||||||||
書誌情報 |
Journal of Magnetism and Magnetic Materials 巻 498, p. 166163-1-166163-9, 発行日 2019-11-21 |
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出版社 | ||||||||||||
出版者 | Elsevier | |||||||||||
DOI | ||||||||||||
関連タイプ | isVersionOf | |||||||||||
識別子タイプ | DOI | |||||||||||
関連識別子 | https://doi.org/10.1016/j.jmmm.2019.166163 | |||||||||||
日本十進分類法 | ||||||||||||
主題Scheme | NDC | |||||||||||
主題 | 459 | |||||||||||
ISSN | ||||||||||||
収録物識別子タイプ | ISSN | |||||||||||
収録物識別子 | 0304-8853 | |||||||||||
著作権関連情報 | ||||||||||||
権利情報 | Copyright (c) 2019 Elsevier B.V. All rights reserved. | |||||||||||
キーワード | ||||||||||||
主題Scheme | Other | |||||||||||
主題 | Nd2Fe14B | |||||||||||
キーワード | ||||||||||||
主題Scheme | Other | |||||||||||
主題 | Crystallographic structure | |||||||||||
キーワード | ||||||||||||
主題Scheme | Other | |||||||||||
主題 | X-ray diffraction | |||||||||||
キーワード | ||||||||||||
主題Scheme | Other | |||||||||||
主題 | High pressure | |||||||||||
キーワード | ||||||||||||
主題Scheme | Other | |||||||||||
主題 | Atomic position | |||||||||||
出版タイプ | ||||||||||||
出版タイプ | AM | |||||||||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||||||||
査読の有無 | ||||||||||||
値 | yes | |||||||||||
研究者情報 | ||||||||||||
https://hyokadb02.jimu.kyutech.ac.jp/html/139_ja.html | ||||||||||||
論文ID(連携) | ||||||||||||
10349788 | ||||||||||||
連携ID | ||||||||||||
8220 | ||||||||||||
資料タイプ | ||||||||||||
内容記述タイプ | Other | |||||||||||
内容記述 | Journal Article | |||||||||||
著者別名 | ||||||||||||
姓名 | Tajiri, T. | |||||||||||
著者別名 | ||||||||||||
姓名 | Mito, Masaki | |||||||||||
言語 | en | |||||||||||
姓名 | 美藤, 正樹 | |||||||||||
言語 | ja | |||||||||||
姓名 | ミトウ, マサキ | |||||||||||
言語 | ja-Kana | |||||||||||
著者所属 | ||||||||||||
Faculty of Science, Fukuoka University, 8-19-1 Nanakuma, Jonan-ku, Fukuoka 814-0180, Japan | ||||||||||||
著者所属 | ||||||||||||
Graduate School of Engineering, Kyushu Institute of Technology, 1-1 Sensui-cho, Tobata-ku, Kitakyushu 804-8550, Japan |