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Superconductivity in the α-Form Layer Structured Metal Nitride Halide
http://hdl.handle.net/10228/00008790
http://hdl.handle.net/10228/00008790c44de30b-c3e6-4e94-837c-c6867c8c3082
名前 / ファイル | ライセンス | アクション |
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condensedmatter-07-00033-v2.pdf (2.5 MB)
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Item type | 学術雑誌論文 = Journal Article(1) | |||||||||||
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公開日 | 2022-04-04 | |||||||||||
資源タイプ | ||||||||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||
資源タイプ | journal article | |||||||||||
タイトル | ||||||||||||
言語 | en | |||||||||||
タイトル | Superconductivity in the α-Form Layer Structured Metal Nitride Halide | |||||||||||
言語 | ||||||||||||
言語 | eng | |||||||||||
著者 |
田中, 将嗣
× 田中, 将嗣
WEKO
22595
× Kataoka, Noriyuki× Yokoya, Takayoshi |
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抄録 | ||||||||||||
内容記述タイプ | Abstract | |||||||||||
内容記述 | Layered metal nitride halides MNX (M = Ti, Zr, Hf; X = Cl, Br, I) have two polymorphs, including α- and β-forms, which have the FeOCl and SmSI structures, respectively. These compounds are band insulators and become metals and show superconductivity after electron doping by intercalating alkali metals between the layers. The superconductivity of β-form had been extensively characterized from decades ago, but it is not easy to consistently interpret all experimental results using conventional phonon-mediated Bardeen–Cooper–Schriefer mechanisms. The titanium compound TiNCl crystallizes only in the α-form structure. TiNCl also exhibits superconductivity as high as ~16 K after electron doping by intercalating metals and/or organic basis. It is important to compare the superconductivity of different M–N networks. However, α-form compounds are vulnerable to moisture, unlike β-form ones. The intercalation compounds are even more sensitive to humid air. Thus, there are few experimental studies on the superconducting mechanism of α-form, although it has been discussed for exotic Cooper-pairing mechanisms. This short review gathers the recent progress in experimental studies of TiNCl. | |||||||||||
言語 | en | |||||||||||
書誌情報 |
en : Condensed Matter 巻 7, 号 2, p. 33-1-33-7, 発行日 2022-04-01 |
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出版社 | ||||||||||||
出版者 | MDPI | |||||||||||
DOI | ||||||||||||
関連タイプ | isIdenticalTo | |||||||||||
識別子タイプ | DOI | |||||||||||
関連識別子 | https://doi.org/10.3390/condmat7020033 | |||||||||||
日本十進分類法 | ||||||||||||
主題Scheme | NDC | |||||||||||
主題 | 427 | |||||||||||
ISSN | ||||||||||||
収録物識別子タイプ | EISSN | |||||||||||
収録物識別子 | 2410-3896 | |||||||||||
著作権関連情報 | ||||||||||||
権利情報Resource | https://creativecommons.org/licenses/by/4.0/ | |||||||||||
権利情報 | Copyright (c) 2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license. | |||||||||||
キーワード | ||||||||||||
主題Scheme | Other | |||||||||||
主題 | α-form layered nitride halides | |||||||||||
キーワード | ||||||||||||
主題Scheme | Other | |||||||||||
主題 | intercalation | |||||||||||
キーワード | ||||||||||||
主題Scheme | Other | |||||||||||
主題 | electron doping | |||||||||||
キーワード | ||||||||||||
主題Scheme | Other | |||||||||||
主題 | superconducting mechanism | |||||||||||
キーワード | ||||||||||||
主題Scheme | Other | |||||||||||
主題 | photoemission spectroscopy | |||||||||||
出版タイプ | ||||||||||||
出版タイプ | VoR | |||||||||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||||
査読の有無 | ||||||||||||
値 | yes | |||||||||||
研究者情報 | ||||||||||||
https://hyokadb02.jimu.kyutech.ac.jp/html/100001006_ja.html | ||||||||||||
論文ID(連携) | ||||||||||||
10389383 | ||||||||||||
連携ID | ||||||||||||
10273 |