{"created":"2023-05-15T11:55:15.887666+00:00","id":114,"links":{},"metadata":{"_buckets":{"deposit":"c8c155a7-b96b-476c-be0f-86b669447fb7"},"_deposit":{"created_by":3,"id":"114","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"114"},"status":"published"},"_oai":{"id":"oai:kyutech.repo.nii.ac.jp:00000114","sets":["8:9"]},"author_link":["535","536","537","538","219","540"],"control_number":"114","item_1689815586683":{"attribute_name":"CRID","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://cir.nii.ac.jp/crid/1050001338909645824","subitem_relation_type_select":"URI"}}]},"item_21_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2006-02-07","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"5","bibliographicPageEnd":"054715-6","bibliographicPageStart":"054715-1","bibliographicVolumeNumber":"124","bibliographic_titles":[{"bibliographic_title":"Journal of Chemical Physics","bibliographic_titleLang":"en"}]}]},"item_21_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"We measured angular distributions of HD and D2 molecules desorbed via the reactions H+D/Si 100 →H+D/Si(100) → HD [abstraction (ABS)] and H+D/Si(100) →D2 [adsorption-induced-desorption (AID)], respectively. It was found that the angular distribution of HD molecules desorbed along ABS is broader than that of D2 molecules desorbed along AID, i.e., the former could be fit withcos2.0±0.2 θ, while the latter with cos5.0±0.5 θ. This difference of the angular distributions between the two reaction paths suggests that their dynamic mechanisms are different. The observed cos2 θ distribution for the ABS reaction was reproduced by the classical trajectory calculations over the London-Eyring-Polanyi-Sato potential-energy surfaces. The simulation suggests that the HD desorption along the ABS path takes place along the direction of Si–D bonds, but the apparent angular distribution is comprised of multiple components reflecting the different orientations of D-occupied Si dimers in the (2×1) and (1×2) double domain structures.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_21_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"affiliations":[{"affiliationNames":[{"lang":"ja"}]}]}]},"item_21_publisher_7":{"attribute_name":"出版社","attribute_value_mlt":[{"subitem_publisher":"American Institute of Physics","subitem_publisher_language":"en"}]},"item_21_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1063/1.2163339","subitem_relation_type_select":"DOI"}}]},"item_21_rights_13":{"attribute_name":"著作権関連情報","attribute_value_mlt":[{"subitem_rights":"Copyright © 2006 American Institute of Physics"}]},"item_21_select_59":{"attribute_name":"査読の有無","attribute_value_mlt":[{"subitem_select_item":"yes"}]},"item_21_source_id_10":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AA00694991","subitem_source_identifier_type":"NCID"}]},"item_21_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1089-7690","subitem_source_identifier_type":"EISSN"},{"subitem_source_identifier":"0021-9606","subitem_source_identifier_type":"PISSN"}]},"item_21_subject_16":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"435","subitem_subject_scheme":"NDC"}]},"item_21_version_type_58":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Inanaga, S.","creatorNameLang":"en"},{"creatorName":"稲永, 征司","creatorNameLang":"ja"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kiyonaga, T.","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Rahman, F.","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Khanom, F.","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorAffiliations":[{"affiliationNames":[{}]}],"creatorNames":[{"creatorName":"Namiki, Akira","creatorNameLang":"en"},{"creatorName":"並木, 章","creatorNameLang":"ja"},{"creatorName":"ナミキ, アキラ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"Lee, J.","creatorNameLang":"en"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2007-11-19"}],"displaytype":"detail","filename":"1.2163339.pdf","filesize":[{"value":"305.7 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"1.2163339.pdf","url":"https://kyutech.repo.nii.ac.jp/record/114/files/1.2163339.pdf"},"version_id":"5ef873f9-9d79-4b77-9309-6fcfb13c299c"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"hydrogen compounds","subitem_subject_scheme":"Other"},{"subitem_subject":"deuterium","subitem_subject_scheme":"Other"},{"subitem_subject":"desorption","subitem_subject_scheme":"Other"},{"subitem_subject":"surface chemistry","subitem_subject_scheme":"Other"},{"subitem_subject":"reaction kinetics","subitem_subject_scheme":"Other"},{"subitem_subject":"otential energy surfaces","subitem_subject_scheme":"Other"},{"subitem_subject":"bonds (chemical)","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Angular distributions of H-induced HD and D2 desorptions from the Si(100) surfaces","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Angular distributions of H-induced HD and D2 desorptions from the Si(100) surfaces","subitem_title_language":"ja"}]},"item_type_id":"21","owner":"3","path":["9"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2007-11-19"},"publish_date":"2007-11-19","publish_status":"0","recid":"114","relation_version_is_last":true,"title":["Angular distributions of H-induced HD and D2 desorptions from the Si(100) surfaces"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2024-04-02T08:38:12.513587+00:00"}