| アイテムタイプ |
学術雑誌論文 = Journal Article(1) |
| 公開日 |
2023-11-15 |
| 資源タイプ |
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資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
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資源タイプ |
journal article |
| タイトル |
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タイトル |
Synthesis and fundamental properties of methacrylate polymer containing five‐membered cyclic trithiocarbonate group |
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言語 |
en |
| 言語 |
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|
言語 |
eng |
| 著者 |
Nishi, Masayuki
Komeda, Masahiro
Aoyagi, Naoto
吉田, 嘉晃
遠藤, 剛
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| 抄録 |
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内容記述タイプ |
Abstract |
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内容記述 |
4-(1,3-Dithia-2-thioxocyclopenthyl)methacrylate (TCMA), containing the five-membered trithiocarbonate moiety, was prepared from glycidyl methacrylate (GMA) through 2,3-epithiopropyl methacrylate (ETMA). At first step, GMA was converted to ETMA by the reaction using thiourea. At second step, ETMA was reacted efficiently with carbon disulfide in the presence of a catalytic amount of 1,2-dimethyltetrahydropyrimidine to give TCMA. The polymerization of TCMA proceeded under standard radical conditions to give the polymeric TCMA in 94% yield. The copolymerizations of TCMA with ethyl acrylate (EA) or acrylonitrile (AN) were conducted by changing the feed molar ratios of the monomers, in which the corresponding copolymers were obtained in over 83% yields. In addition, the obtained polymers showed the high values of refractive index over ca. 1.6 due to the presence of the cyclic trithiocarbonate structure. |
|
言語 |
en |
| 書誌情報 |
en : Journal of Polymer Science
巻 58,
号 15,
p. 2126-2133,
発行日 2020-08-01
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| 出版社 |
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出版者 |
Wiley |
| DOI |
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識別子タイプ |
DOI |
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関連識別子 |
https://doi.org/10.1002/pol.20200201 |
| ISSN |
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収録物識別子タイプ |
EISSN |
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収録物識別子 |
2642-4169 |
| 著作権関連情報 |
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権利情報 |
Copyright (c) 2020 Wiley Periodicals LLC |
| 出版タイプ |
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出版タイプ |
AM |
|
出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
| 査読の有無 |
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|
値 |
yes |
| 研究者情報 |
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|
URL |
https://hyokadb02.jimu.kyutech.ac.jp/html/100001233_ja.html |
10.1002_pol.20200201.pdf (1 MB)
