| アイテムタイプ |
学術雑誌論文 = Journal Article(1) |
| 公開日 |
2024-05-13 |
| 資源タイプ |
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資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
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資源タイプ |
journal article |
| タイトル |
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|
タイトル |
Impacts of negatively charged colloidal clay particles on photoisomerization of both anionic and cationic azobenzene molecules |
|
言語 |
en |
| 言語 |
|
|
言語 |
eng |
| 著者 |
毛利, 恵美子
Kajiwara, Kei
Kawasaki, Shuhei
Shimizu, Yusuke
Bando, Hikaru
Sakai, Hideki
中戸, 晃之
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| 抄録 |
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内容記述タイプ |
Abstract |
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内容記述 |
Although smectite-type clays are used as heterogeneous media for photofunctional guest molecules, the guest species are limited to cationic or polar molecules because of the intrinsic negative electric charges of clay particles. Nevertheless, in this study, aqueous clay colloids are reported to affect the photoisomerization kinetics of anionic and cationic azobenzene molecules dissolved in the colloids. Under UV-light irradiation, the clay colloids decelerate trans-to-cis isomerization, while under visible-light irradiation, the clay colloids accelerate cis-to-trans isomerization. In addition, the sol–gel transition of clay colloids affects the kinetics. The results considerably expand the applicability of clay colloids as matrixes for functional organic species. |
|
言語 |
en |
| 書誌情報 |
en : RSC Advances
巻 12,
号 17,
p. 10855-10861,
発行日 2022-04-07
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| 出版社 |
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出版者 |
Royal Society of Chemistry |
|
言語 |
en |
| DOI |
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|
関連タイプ |
isIdenticalTo |
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|
識別子タイプ |
DOI |
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|
関連識別子 |
https://doi.org/10.1039/D2RA01020H |
| ISSN |
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収録物識別子タイプ |
EISSN |
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収録物識別子 |
2046-2069 |
| 著作権関連情報 |
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権利情報Resource |
http://creativecommons.org/licenses/by/3.0/ |
|
権利情報 |
Copyright (c) 2022 The Author(s). Published by the Royal Society of Chemistry. This article is Open Access |
| 出版タイプ |
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|
出版タイプ |
VoR |
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出版タイプResource |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
| 査読の有無 |
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|
値 |
yes |
| 研究者情報 |
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|
URL |
https://hyokadb02.jimu.kyutech.ac.jp/html/100000325_ja.html |
| 研究者情報 |
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|
URL |
https://hyokadb02.jimu.kyutech.ac.jp/html/122_ja.html |
| 論文ID（連携） |
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|
値 |
10402114 |
| 連携ID |
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|
値 |
12248 |
10402114.pdf (761 KB)
