@article{oai:kyutech.repo.nii.ac.jp:00004284, author = {Saigyo, Hibiki and Hori, Hiroki and Tsukamoto, Takuma and Yamase, Ryota and Hario, Kensuke and Tsuruta, Kazuki and Deguchi, Hiroyuki and 出口, 博之 and Mito, Masaki and 美藤, 正樹 and Tajiri, Takayuki and Akimaru, Hinako and Kawai, Yoshiki and Tanaka, Miki and Taninaga, Mika and Tomikawa, Mei and Nakahara, Takeru and Matsumura, Ryogo and Mimura, Yoshihisa and Myoga, Takaki and Muramoto, Tomoka and Yoshitake, Takumi and Wada, Yuuma and Okazaki, Akira and Kimura, Kana and Mizobe, Tomoki and Miyauchi, Kaho and Onmura, Yuga and Ichishima, Kei}, issue = {8}, journal = {Journal of the Ceramic Society of Japan}, month = {}, note = {Hagi ware originally consists of a mixture of two raw materials: Daido clay and Mishima clay. During its firing process, we observed a change in the magnetic properties of the iron oxide, Fe2O3. The magnetic moment of the Daido clay (which only contains a small amount of the Fe2O3 γ-phase) attains a maximum at a firing temperature of approximately 600°C, where a minor amount of the poorly crystallized Fe2O3 temporarily changes to the ferromagnetic γ-phase. Furthermore, the magnetic moment of the Mishima clay (which contains a large amount of the Fe2O3 γ-phase) decreases as the firing temperature increases, whereas the coercive field rapidly increases at firing temperatures above 1000°C. The magnetization curve of the Mishima clay that was fired at temperatures above 1200°C is characteristic of a two-component system consisting of a minor γ-phase and a major α-phase. The above-mentioned phenomena were also confirmed by XRD analyses. A series of experiments indicated that the firing of Hagi ware can be characterized as a transformation from the γ-phase of Fe2O3 to the α-phase of Fe2O3. This transformation is considered to contribute to the change from soft magnetism to hard magnetism of Hagi ware.}, pages = {649--655}, title = {Magnetic Properties of Hagi Ware}, volume = {123}, year = {2015}, yomi = {デグチ, ヒロユキ and ミトウ, マサキ} }