{"created":"2023-05-15T11:58:20.655401+00:00","id":4323,"links":{},"metadata":{"_buckets":{"deposit":"e0bda69c-7764-4831-9d58-87ffa1bd8b7d"},"_deposit":{"created_by":3,"id":"4323","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"4323"},"status":"published"},"_oai":{"id":"oai:kyutech.repo.nii.ac.jp:00004323","sets":["8:9"]},"author_link":["15664","15666","6369"],"item_21_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2015-12-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"4","bibliographicPageEnd":"411","bibliographicPageStart":"407","bibliographicVolumeNumber":"3","bibliographic_titles":[{"bibliographic_title":"Journal of Asian Ceramic Societies"}]}]},"item_21_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Apatite-polymer composites have been evaluated in terms of its potential application as bone substitutes. Biomimetic processes using simulated body fluid (SBF) are well-known methods for preparation of such composites. They are reliant on specific functional groups to induce the heterogeneous apatite nucleation and phosphate groups possess good apatite-forming ability in SBF. Improving the degree of polymerization is important for obtaining phosphate-containing polymers, because the release of significant quantities of monomer or low molecular weight polymers can lead to suppression of the apatite formation. To date, there have been very few studies pertaining to the effect of adding a polymerization accelerator to the polymerization reaction involved in the formation of these composite materials under physiological conditions. In this study, we have prepared a copolymer from triethylene glycol dimethacrylate and vinylphosphonic acid (VPA) in the presence of different amounts of sodium p-toluenesulfinate (p-TSS) as a polymerization accelerator. The effects of p-TSS on the chemical durability and apatite formation of the copolymers were investigated in SBF. The addition of 0.1–1.0 wt% of p-TSS was effective for suppressing the dissolution of the copolymers in SBF, whereas larger amount had a detrimental effect. A calcium polyvinylphosphate instead of the apatite was precipitated in SBF.","subitem_description_type":"Abstract"}]},"item_21_description_60":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Journal Article","subitem_description_type":"Other"}]},"item_21_link_62":{"attribute_name":"研究者情報","attribute_value_mlt":[{"subitem_link_url":"https://hyokadb02.jimu.kyutech.ac.jp/html/323_ja.html"}]},"item_21_publisher_7":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier"}]},"item_21_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1016/j.jascer.2015.09.001","subitem_relation_type_select":"DOI"}}]},"item_21_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright (c) 2015 The Ceramic Society of Japan and the Korean Ceramic Society. Production and hosting by Elsevier B.V. A"}]},"item_21_select_59":{"attribute_name":"査読の有無","attribute_value_mlt":[{"subitem_select_item":"yes"}]},"item_21_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"2187-0764","subitem_source_identifier_type":"ISSN"}]},"item_21_text_36":{"attribute_name":"著者所属","attribute_value_mlt":[{"subitem_text_value":"Graduate School of Life Science and Systems Engineering, Kyushu Institute of Technology"},{"subitem_text_value":"Frontier Research Academy for Young Researchers, Kyushu Institute of Technology"},{"subitem_text_value":"Graduate School of Life Science and Systems Engineering, Kyushu Institute of Technology"}]},"item_21_text_63":{"attribute_name":"連携ID","attribute_value_mlt":[{"subitem_text_value":"5263"}]},"item_21_version_type_58":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Hamai, Ryo"}],"nameIdentifiers":[{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"Shirosaki, Yuki","creatorNameLang":"en"},{"creatorName":"城崎, 由紀","creatorNameLang":"ja"},{"creatorName":"シロサキ, ユキ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{},{},{},{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"Miyazaki, Toshiki","creatorNameLang":"en"},{"creatorName":"宮崎, 敏樹","creatorNameLang":"ja"},{"creatorName":"ミヤザキ, トシキ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{},{},{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-01-05"}],"displaytype":"detail","filename":"JASCER-D-15-00071R1.pdf","filesize":[{"value":"1.3 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"JASCER-D-15-00071R1.pdf","url":"https://kyutech.repo.nii.ac.jp/record/4323/files/JASCER-D-15-00071R1.pdf"},"version_id":"52f17db1-f68c-4249-b5a4-7b590f255f98"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Simulated body fluid","subitem_subject_scheme":"Other"},{"subitem_subject":"Biomimetic process","subitem_subject_scheme":"Other"},{"subitem_subject":"Organic-inorganic composites","subitem_subject_scheme":"Other"},{"subitem_subject":"Phosphate group","subitem_subject_scheme":"Other"},{"subitem_subject":"Sodium p-toluenesulfinate","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Biomineralization Behavior of a Vinylphosphonic acid-based Copolymer Added with Polymerization Accelerator in Simulated Body Fluid","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Biomineralization Behavior of a Vinylphosphonic acid-based Copolymer Added with Polymerization Accelerator in Simulated Body Fluid"}]},"item_type_id":"21","owner":"3","path":["9"],"pubdate":{"attribute_name":"公開日","attribute_value":"2016-01-05"},"publish_date":"2016-01-05","publish_status":"0","recid":"4323","relation_version_is_last":true,"title":["Biomineralization Behavior of a Vinylphosphonic acid-based Copolymer Added with Polymerization Accelerator in Simulated Body Fluid"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2024-04-02T08:44:16.501892+00:00"}