{"created":"2023-05-15T11:59:00.702691+00:00","id":5262,"links":{},"metadata":{"_buckets":{"deposit":"d4086a07-68c7-4782-8515-f95a34edc5af"},"_deposit":{"created_by":3,"id":"5262","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"5262"},"status":"published"},"_oai":{"id":"oai:kyutech.repo.nii.ac.jp:00005262","sets":["8:24"]},"author_link":["21175","21177","21176","6794"],"item_21_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1998-09","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"9","bibliographicPageEnd":"878","bibliographicPageStart":"877","bibliographicVolumeNumber":"27","bibliographic_titles":[{"bibliographic_title":"Chemistry Letters"}]}]},"item_21_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Photocatalytic oxidation of 2-hexene on TiO2 powder was investigated under a stream of oxygen gas. The main product was 2,3-epoxyhexane with the chemical yield ranging from 65% to 83% depending on the TiO2 powders. When trans-2-hexene was used as the starting material, the epoxide was also trans. On the other hand, cis epoxide was the chief product from cis-2-hexene. From mixed 2-hexene (trans/cis = 1.7), larger amounts of trans epoxide were obtained than cis-epoxide in the initial period of the reaction, indicating that trans-2-hexene is more reactive than the cis isomer on the photocatalyst.","subitem_description_type":"Abstract"}]},"item_21_description_60":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Journal Article","subitem_description_type":"Other"}]},"item_21_link_62":{"attribute_name":"研究者情報","attribute_value_mlt":[{"subitem_link_url":"https://hyokadb02.jimu.kyutech.ac.jp/html/98_ja.html"}]},"item_21_publisher_7":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"公益社団法人日本化学会"}]},"item_21_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1246/cl.1998.877","subitem_relation_type_select":"DOI"}}]},"item_21_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright (c) 1998 The Chemical Society of Japan"}]},"item_21_select_59":{"attribute_name":"査読の有無","attribute_value_mlt":[{"subitem_select_item":"yes"}]},"item_21_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00603318","subitem_source_identifier_type":"NCID"}]},"item_21_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0366-7022","subitem_source_identifier_type":"ISSN"},{"subitem_source_identifier":"1348-0715","subitem_source_identifier_type":"ISSN"}]},"item_21_text_28":{"attribute_name":"論文ID（連携）","attribute_value_mlt":[{"subitem_text_value":"10025781"}]},"item_21_text_36":{"attribute_name":"著者所属","attribute_value_mlt":[{"subitem_text_value":"Research Center for Photoenergetics of Organic Materials, Osaka University"},{"subitem_text_value":"Research Center for Photoenergetics of Organic Materials, Osaka University"},{"subitem_text_value":"Research Center for Photoenergetics of Organic Materials, Osaka University"},{"subitem_text_value":"Research Center for Photoenergetics of Organic Materials, Osaka University"}]},"item_21_text_63":{"attribute_name":"連携ID","attribute_value_mlt":[{"subitem_text_value":"6352"}]},"item_21_version_type_58":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"Ohno, Teruhisa","creatorNameLang":"en"},{"creatorName":"横野, 照尚","creatorNameLang":"ja"},{"creatorName":"オウノ, テルヒサ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{},{},{},{}]},{"creatorNames":[{"creatorName":"Kigoshi,  Takayo"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Nakabeya,  Keizo"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Matsumura,  Michio"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-12-25"}],"displaytype":"detail","filename":"CL27_877.pdf","filesize":[{"value":"631.8 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"CL27_877.pdf","url":"https://kyutech.repo.nii.ac.jp/record/5262/files/CL27_877.pdf"},"version_id":"e89902e1-f9c0-43f9-a9a2-65b4588d0825"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Stereospecific Epoxidation of 2-Hexene with Molecular Oxygen on Photoirradiated Titanium Dioxide Powder","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Stereospecific Epoxidation of 2-Hexene with Molecular Oxygen on Photoirradiated Titanium Dioxide Powder"}]},"item_type_id":"21","owner":"3","path":["24"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-12-25"},"publish_date":"2017-12-25","publish_status":"0","recid":"5262","relation_version_is_last":true,"title":["Stereospecific Epoxidation of 2-Hexene with Molecular Oxygen on Photoirradiated Titanium Dioxide Powder"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-10-25T07:52:06.953188+00:00"}