{"created":"2023-05-15T11:59:02.808951+00:00","id":5310,"links":{},"metadata":{"_buckets":{"deposit":"30574ddb-8a93-47fe-93c5-936622e0279f"},"_deposit":{"created_by":3,"id":"5310","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"5310"},"status":"published"},"_oai":{"id":"oai:kyutech.repo.nii.ac.jp:00005310","sets":["8:24"]},"author_link":["21363","21373","21368","21370","27551","21371","21372","1375","21369","21367","6794"],"control_number":"5310","item_21_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2013-05-30","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"21","bibliographicPageEnd":"11016","bibliographicPageStart":"11008","bibliographicVolumeNumber":"117","bibliographic_titles":[{"bibliographic_title":"The Journal of physical chemistry. C","bibliographic_titleLang":"en"}]}]},"item_21_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A rhodium(III) ion (Rh3+)-modified TiO2 (Rh3+/TiO2) photocatalyst, prepared by a simple adsorption method and exhibiting high levels of photocatalytic activity in degradation of organic compounds, was investigated by using X-ray absorption fine structure (XAFS) measurements, (photo)electrochemical measurements, double-beam photoacoustic (DB-PA) spectroscopic measurements, and photoluminescence measurements. Based on the results, the features of the Rh3+ modifier and the working mechanism of the Rh3+/TiO2 photocatalyst are discussed. XAFS measurements revealed that the Rh3+ species were highly dispersed and almost atomically isolated on TiO2. The (photo)electrochemical measurements, DB-PA spectroscopic measurements, and photoluminescence showed a unique bifunction of the Rh3+ modifier as a promoter for O2 reductions and an electron injector to the conduction band of TiO2 for response to visible light. The reasons for the Rh3+/TiO2 photocatalyst exhibiting higher levels of photocatalytic activity than those of TiO2 photocatalysts modified with other metal ions are also discussed on the basis of obtained results.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_21_link_62":{"attribute_name":"研究者情報","attribute_value_mlt":[{"subitem_link_url":"https://hyokadb02.jimu.kyutech.ac.jp/html/98_ja.html"}]},"item_21_publisher_7":{"attribute_name":"出版社","attribute_value_mlt":[{"subitem_publisher":"American Chemical Society","subitem_publisher_language":"en"}]},"item_21_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1021/jp311801e","subitem_relation_type_select":"DOI"}}]},"item_21_rights_13":{"attribute_name":"著作権関連情報","attribute_value_mlt":[{"subitem_rights":"Copyright (c) 2013 American Chemical Society. This material is excerpted from a work that was accepted for publication in Journal of Physical Chemistry C, copyright © American Chemical Society after peer review. To access the final edited and published work see http://pubs.acs.org/doi/abs/10.1021/jp311801e."}]},"item_21_select_59":{"attribute_name":"査読の有無","attribute_value_mlt":[{"subitem_select_item":"yes"}]},"item_21_source_id_10":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AA1217589X","subitem_source_identifier_type":"NCID"}]},"item_21_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1932-7455","subitem_source_identifier_type":"EISSN"},{"subitem_source_identifier":"1932-7447","subitem_source_identifier_type":"PISSN"}]},"item_21_text_28":{"attribute_name":"論文ID（連携）","attribute_value_mlt":[{"subitem_text_value":"10304350"}]},"item_21_text_63":{"attribute_name":"連携ID","attribute_value_mlt":[{"subitem_text_value":"6468"}]},"item_21_version_type_58":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kitano, Sho","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorAffiliations":[{"affiliationNames":[{}]}],"creatorNames":[{"creatorName":"Murakami, Naoya","creatorNameLang":"en"},{"creatorName":"村上, 直也","creatorNameLang":"ja"},{"creatorName":"ムラカミ, ナオヤ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{},{},{},{}]},{"creatorAffiliations":[{"affiliationNames":[{}]}],"creatorNames":[{"creatorName":"Ohno, Teruhisa","creatorNameLang":"en"},{"creatorName":"横野, 照尚","creatorNameLang":"ja"},{"creatorName":"オウノ, テルヒサ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{},{},{},{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"Mitani, Yasunori","creatorNameLang":"en"},{"creatorName":"三谷, 康範","creatorNameLang":"ja"},{"creatorName":"ミタニ, ヤスノリ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{},{},{}]},{"creatorNames":[{"creatorName":"Nosaka, Yoshio","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Asakura, Hiroyuki","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Teramura, Kentaro","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Tanaka, Tsunehiro","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Tada, Hiroaki","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Hashimoto, Keiji","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kominami, Hiroshi","creatorNameLang":"en"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-01-23"}],"displaytype":"detail","filename":"JPCC117_11008.pdf","filesize":[{"value":"1.7 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"JPCC117_11008.pdf","url":"https://kyutech.repo.nii.ac.jp/record/5310/files/JPCC117_11008.pdf"},"version_id":"1f23e6e5-d958-45c9-aa86-81c17bf68499"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Bifunctionality of Rh3+ Modifier on TiO2 and Working Mechanism of Rh3+/TiO2 Photocatalyst under Irradiation of Visible Light","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Bifunctionality of Rh3+ Modifier on TiO2 and Working Mechanism of Rh3+/TiO2 Photocatalyst under Irradiation of Visible Light","subitem_title_language":"en"}]},"item_type_id":"21","owner":"3","path":["24"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2018-01-23"},"publish_date":"2018-01-23","publish_status":"0","recid":"5310","relation_version_is_last":true,"title":["Bifunctionality of Rh3+ Modifier on TiO2 and Working Mechanism of Rh3+/TiO2 Photocatalyst under Irradiation of Visible Light"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2024-04-26T02:08:40.315112+00:00"}