{"created":"2023-05-15T11:59:05.084209+00:00","id":5356,"links":{},"metadata":{"_buckets":{"deposit":"b0c6635d-2fd3-4bd3-aebf-50b1bdc2eda6"},"_deposit":{"created_by":3,"id":"5356","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"5356"},"status":"published"},"_oai":{"id":"oai:kyutech.repo.nii.ac.jp:00005356","sets":["8:24"]},"author_link":["21550","21549","27551","6794"],"item_21_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2012-05-15","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"15","bibliographicPageEnd":"5809","bibliographicPageStart":"5803","bibliographicVolumeNumber":"258","bibliographic_titles":[{"bibliographic_title":"Applied Surface Science"}]}]},"item_21_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Surface morphology of brookite titanium dioxide (TiO2) nanorods was modified by chemical etching with aqueous hydrogen (H2O2)–ammonia (NH3) or sulfuric acid (H2SO4) solution. The brookite nanorods after chemical etching were characterized by TEM, SAED, FE-SEM, XRD and specific surface area measurements. Brookite nanorods after chemical etching with H2O2–NH3 solution exposed new crystal faces in the tips, and nanorods with sharper tips were observed. On the other hand, etching with H2SO4 at 200 °C induced morphological changes in the tip faces and broadened the angle between tip faces as a result of dissolution along the [0 0 1] direction, though brookite nanorods were only slightly etched after etching with H2SO4 at room temperature. Photocatalytic activity of brookite nanorods was tested by toluene decomposition in gas phase under ultraviolet irradiation. Brookite nanorods etched with H2O2–NH3 solution showed higher photocatalytic activity than that of brookite nanorods before etching. In the case of H2SO4 etching at 200 °C, brookite nanorods after etching exhibited lower photocatalytic activity. One reason for this may be that the formation of newly exposed crystal faces by H2O2–NH3 etching improved separation of redox sites due to their strong oxidation ability.","subitem_description_type":"Abstract"}]},"item_21_description_60":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Journal Article","subitem_description_type":"Other"}]},"item_21_link_62":{"attribute_name":"研究者情報","attribute_value_mlt":[{"subitem_link_url":"https://hyokadb02.jimu.kyutech.ac.jp/html/98_ja.html"}]},"item_21_publisher_7":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier"}]},"item_21_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1016/j.apsusc.2012.02.103","subitem_relation_type_select":"DOI"}}]},"item_21_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright (c) 2012 Elsevier B.V."}]},"item_21_select_59":{"attribute_name":"査読の有無","attribute_value_mlt":[{"subitem_select_item":"yes"}]},"item_21_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA1152169X","subitem_source_identifier_type":"NCID"}]},"item_21_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0169-4332","subitem_source_identifier_type":"ISSN"}]},"item_21_text_28":{"attribute_name":"論文ID（連携）","attribute_value_mlt":[{"subitem_text_value":"10225304"}]},"item_21_text_36":{"attribute_name":"著者所属","attribute_value_mlt":[{"subitem_text_value":"Department of Materials Science, Faculty of Engineering, Kyushu Institute of Technology"},{"subitem_text_value":"Department of Materials Science, Faculty of Engineering, Kyushu Institute of Technology"},{"subitem_text_value":"Department of Materials Science, Faculty of Engineering, Kyushu Institute of Technology"},{"subitem_text_value":"Department of Materials Science, Faculty of Engineering, Kyushu Institute of Technology, JST, PRESTO"}]},"item_21_text_63":{"attribute_name":"連携ID","attribute_value_mlt":[{"subitem_text_value":"6562"}]},"item_21_version_type_58":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Zhanga,  Linjie"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Menendez-Floresa,  Victor M."}],"nameIdentifiers":[{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"Murakami, Naoya","creatorNameLang":"en"},{"creatorName":"村上, 直也","creatorNameLang":"ja"},{"creatorName":"ムラカミ, ナオヤ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{},{},{},{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"Ohno, Teruhisa","creatorNameLang":"en"},{"creatorName":"横野, 照尚","creatorNameLang":"ja"},{"creatorName":"オウノ, テルヒサ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{},{},{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-02-16"}],"displaytype":"detail","filename":"ASS258-5803.pdf","filesize":[{"value":"610.7 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"ASS258-5803.pdf","url":"https://kyutech.repo.nii.ac.jp/record/5356/files/ASS258-5803.pdf"},"version_id":"3ff15daf-29ef-4210-b81d-d85c2f0ab0f8"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Photocatalyst","subitem_subject_scheme":"Other"},{"subitem_subject":"Brookite nanorods","subitem_subject_scheme":"Other"},{"subitem_subject":"Chemical etching","subitem_subject_scheme":"Other"},{"subitem_subject":"Redox site","subitem_subject_scheme":"Other"},{"subitem_subject":"Photocatalytic activity","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Improvement of photocatalytic activity of brookite titanium dioxide nanorods by surface modification using chemical etching","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Improvement of photocatalytic activity of brookite titanium dioxide nanorods by surface modification using chemical etching"}]},"item_type_id":"21","owner":"3","path":["24"],"pubdate":{"attribute_name":"公開日","attribute_value":"2018-02-16"},"publish_date":"2018-02-16","publish_status":"0","recid":"5356","relation_version_is_last":true,"title":["Improvement of photocatalytic activity of brookite titanium dioxide nanorods by surface modification using chemical etching"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-10-25T10:05:25.927628+00:00"}