{"created":"2023-05-15T11:59:05.249648+00:00","id":5360,"links":{},"metadata":{"_buckets":{"deposit":"2cbc8232-a6c4-46eb-a4ba-8a60411bf4fe"},"_deposit":{"created_by":3,"id":"5360","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"5360"},"status":"published"},"_oai":{"id":"oai:kyutech.repo.nii.ac.jp:00005360","sets":["8:24"]},"author_link":["21571","7315","21572","27551","21568","6794","21570"],"item_21_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2014-06-25","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"316","bibliographicPageStart":"309","bibliographicVolumeNumber":"152-153","bibliographic_titles":[{"bibliographic_title":"Applied Catalysis B: Environmental"}]}]},"item_21_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Photocatalytic reduction of carbon dioxide (CO2) was carried out using exposed-crystal- face-controlled titanium(IV) oxide (TiO2) having a brookite phase. Methanol (CH3OH) was detected as the main product, and trace amounts of formic acid, carbon monoxide, methane, and hydrogen were also detected in some cases. The prepared nanorod-shaped brookite TiO2 with large {2 1 0} and small {2 1 2} exposed crystal faces showed larger CH3OH generation than that of commercial brookite TiO2 powder (Kojundo Chemical Laboratory Co., Ltd.). The activity of a brookite TiO2 nanorod for CO2 reduction depended on its aspect ratio because the {2 1 0} crystal faced worked as a reduction site, whereas an oxidation site was assigned to {2 1 2} crystal faces. Photodeposition of gold (Au) or silver (Ag) nanoparticles on the nanorod-shaped brookite TiO2 induced a dramatic increase in CH3OH production because the deposited metal particles work as reductive sites for multi-electron reduction of CO2. Among the co-catalyst-loaded brookite TiO2 nanorods, nanorod-shaped brookite TiO2 loaded with Ag showed higher activity. The source of carbon of CH3OH obtained by CO2 reduction is discussed on the basis of results of a labeling experiment using 13CO2.","subitem_description_type":"Abstract"}]},"item_21_description_60":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Journal Article","subitem_description_type":"Other"}]},"item_21_link_62":{"attribute_name":"研究者情報","attribute_value_mlt":[{"subitem_link_url":"https://hyokadb02.jimu.kyutech.ac.jp/html/98_ja.html"}]},"item_21_publisher_7":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier"}]},"item_21_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1016/j.apcatb.2014.01.048","subitem_relation_type_select":"DOI"}}]},"item_21_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright (c) 2014 Elsevier B.V. All rights reserved"}]},"item_21_select_59":{"attribute_name":"査読の有無","attribute_value_mlt":[{"subitem_select_item":"yes"}]},"item_21_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA1082551X","subitem_source_identifier_type":"NCID"}]},"item_21_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0926-3373","subitem_source_identifier_type":"ISSN"}]},"item_21_text_28":{"attribute_name":"論文ID（連携）","attribute_value_mlt":[{"subitem_text_value":"10254922"}]},"item_21_text_36":{"attribute_name":"著者所属","attribute_value_mlt":[{"subitem_text_value":"Department of Materials Science, Faculty of Engineering, Kyushu Institute of Technology, JST, PRESTO, JST, ACT-C"},{"subitem_text_value":"Department of Materials Science, Faculty of Engineering, Kyushu Institute of Technology"},{"subitem_text_value":"Department of Materials Science, Faculty of Engineering, Kyushu Institute of Technology, JST, ACT-C"},{"subitem_text_value":"Department of Materials Science, Faculty of Engineering, Kyushu Institute of Technology"},{"subitem_text_value":"Department of Materials Science, Faculty of Engineering, Kyushu Institute of Technology"},{"subitem_text_value":"Department of Materials Science, Faculty of Engineering, Kyushu Institute of Technology"},{"subitem_text_value":"Department of Materials Science, Faculty of Engineering, Kyushu Institute of Technology"}]},"item_21_text_63":{"attribute_name":"連携ID","attribute_value_mlt":[{"subitem_text_value":"6574"}]},"item_21_version_type_58":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"Ohno, Teruhisa","creatorNameLang":"en"},{"creatorName":"横野, 照尚","creatorNameLang":"ja"},{"creatorName":"オウノ, テルヒサ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{},{},{},{}]},{"creatorNames":[{"creatorName":"Higo,  Takayoshi"}],"nameIdentifiers":[{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"Murakami, Naoya","creatorNameLang":"en"},{"creatorName":"村上, 直也","creatorNameLang":"ja"},{"creatorName":"ムラカミ, ナオヤ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{},{},{},{}]},{"creatorNames":[{"creatorName":"Saito,  Hirofumi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Zhang,  Qitao"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yang,  Yin"}],"nameIdentifiers":[{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"Tsubota, Toshiki","creatorNameLang":"en"},{"creatorName":"坪田, 敏樹","creatorNameLang":"ja"},{"creatorName":"ツボタ, トシキ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{},{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-02-16"}],"displaytype":"detail","filename":"ACBE152_309.pdf","filesize":[{"value":"1.3 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"ACBE152_309.pdf","url":"https://kyutech.repo.nii.ac.jp/record/5360/files/ACBE152_309.pdf"},"version_id":"2a3737a0-6d11-4d17-8b16-59a31bd4884d"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Exposed-crystal-face-controlled TiO2","subitem_subject_scheme":"Other"},{"subitem_subject":"Brookite TiO2 nanorod","subitem_subject_scheme":"Other"},{"subitem_subject":"Separation of reaction sites","subitem_subject_scheme":"Other"},{"subitem_subject":"Reduction of carbon dioxide","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Photocatalytic reduction of CO2 over exposed-crystal-face-controlled TiO2 nanorod having a brookite phase with co-catalyst loading","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Photocatalytic reduction of CO2 over exposed-crystal-face-controlled TiO2 nanorod having a brookite phase with co-catalyst loading"}]},"item_type_id":"21","owner":"3","path":["24"],"pubdate":{"attribute_name":"公開日","attribute_value":"2018-02-16"},"publish_date":"2018-02-16","publish_status":"0","recid":"5360","relation_version_is_last":true,"title":["Photocatalytic reduction of CO2 over exposed-crystal-face-controlled TiO2 nanorod having a brookite phase with co-catalyst loading"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-10-25T10:05:29.462800+00:00"}