{"created":"2023-05-15T11:59:05.706881+00:00","id":5371,"links":{},"metadata":{"_buckets":{"deposit":"1b0109b6-a004-4dc2-aa15-1bc606d6f67b"},"_deposit":{"created_by":3,"id":"5371","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"5371"},"status":"published"},"_oai":{"id":"oai:kyutech.repo.nii.ac.jp:00005371","sets":["8:24"]},"author_link":["21627","21626","21628","6794"],"item_21_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2001-11-15","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"168","bibliographicPageStart":"163","bibliographicVolumeNumber":"204","bibliographic_titles":[{"bibliographic_title":"Journal of Catalysis"}]}]},"item_21_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"1-Decene was converted to 1,2-epoxydecane on UV-irradiated TiO2 powder using molecular oxygen as the oxygen source. Other main products were nonanal and 2-decanone. For anatase-form TiO2 powders, the reaction rate was hardly affected by addition of hydrogen peroxide to the solution. In contrast, for rutile-form TiO2 powders, the rate of epoxide generation was significantly increased by addition of hydrogen peroxide. In this case, the reaction occurred under visible light as well as UV light. The selectivity of the production of 1,2-epoxydecane was higher under visible light than under UV light. The conversion efficiency of an incident photon to 1,2-epoxydecane was about 2% when irradiated with visible light in the range 440–480 nm. UV–visible diffuse reflection spectroscopy, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy suggested the generation of a Ti–η2-peroxide on rutile TiO2 surface after treatment with hydrogen peroxide. The initial step of the reaction under visible light was attributed to a photochemical reaction of this peroxide with 1-decene.","subitem_description_type":"Abstract"}]},"item_21_description_60":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Journal Article","subitem_description_type":"Other"}]},"item_21_link_62":{"attribute_name":"研究者情報","attribute_value_mlt":[{"subitem_link_url":"https://hyokadb02.jimu.kyutech.ac.jp/html/98_ja.html"}]},"item_21_publisher_7":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier"}]},"item_21_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1006/jcat.2001.3384","subitem_relation_type_select":"DOI"}}]},"item_21_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright © 2001 Academic Press"}]},"item_21_select_59":{"attribute_name":"査読の有無","attribute_value_mlt":[{"subitem_select_item":"yes"}]},"item_21_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0021-9517","subitem_source_identifier_type":"ISSN"}]},"item_21_text_28":{"attribute_name":"論文ID（連携）","attribute_value_mlt":[{"subitem_text_value":"10047903"}]},"item_21_text_36":{"attribute_name":"著者所属","attribute_value_mlt":[{"subitem_text_value":"Research Center for Solar Energy Chemistry, Osaka University"},{"subitem_text_value":"Research Center for Solar Energy Chemistry, Osaka University"},{"subitem_text_value":"Research Center for Solar Energy Chemistry, Osaka University"},{"subitem_text_value":"Research Center for Solar Energy Chemistry, Osaka University"}]},"item_21_text_63":{"attribute_name":"連携ID","attribute_value_mlt":[{"subitem_text_value":"6557"}]},"item_21_version_type_58":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"Ohno, Teruhisa","creatorNameLang":"en"},{"creatorName":"横野, 照尚","creatorNameLang":"ja"},{"creatorName":"オウノ, テルヒサ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{},{},{},{}]},{"creatorNames":[{"creatorName":"Masaki,  Yuji"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Hirayama,  Seiko"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Matsumura,  Michio"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-02-22"}],"displaytype":"detail","filename":"JC204_163.pdf","filesize":[{"value":"986.3 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"JC204_163.pdf","url":"https://kyutech.repo.nii.ac.jp/record/5371/files/JC204_163.pdf"},"version_id":"ca55d499-d7b4-49dd-83e7-223d7cdb6ca6"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"titanium dioxide","subitem_subject_scheme":"Other"},{"subitem_subject":"epoxide","subitem_subject_scheme":"Other"},{"subitem_subject":"hydrogen peroxide","subitem_subject_scheme":"Other"},{"subitem_subject":"visible light","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"TiO2-Photocatalyzed Epoxidation of 1-Decene by H2O2 under Visible Light","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"TiO2-Photocatalyzed Epoxidation of 1-Decene by H2O2 under Visible Light"}]},"item_type_id":"21","owner":"3","path":["24"],"pubdate":{"attribute_name":"公開日","attribute_value":"2018-02-22"},"publish_date":"2018-02-22","publish_status":"0","recid":"5371","relation_version_is_last":true,"title":["TiO2-Photocatalyzed Epoxidation of 1-Decene by H2O2 under Visible Light"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-10-25T07:52:09.344400+00:00"}