{"created":"2023-05-15T11:59:12.445141+00:00","id":5527,"links":{},"metadata":{"_buckets":{"deposit":"45bbc7b5-997c-473c-ba11-633595d907d2"},"_deposit":{"created_by":3,"id":"5527","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"5527"},"status":"published"},"_oai":{"id":"oai:kyutech.repo.nii.ac.jp:00005527","sets":["8:24"]},"author_link":["21654","22374","21961","22006"],"control_number":"5527","item_21_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2009-09-16","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"20","bibliographicPageEnd":"7935","bibliographicPageStart":"7930","bibliographicVolumeNumber":"42","bibliographic_titles":[{"bibliographic_title":"Macromolecules","bibliographic_titleLang":"en"}]}]},"item_21_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Polystyrene (PSt)-based copolymer/montmorillonite (MMT) nanocomposites were prepared by an in-situ vapor-phase assisted surface polymerization (VASP) as a solventless method using an organically modified MMT and a free radical initiator. Simultaneous and consecutive VASP of styrene (St) and methyl methacrylate (MMA) on the pre-modified MMT induced the accumulation of poly(MMA-ran-St) and poly(MMA-block-St) on the MMT surface, resulting in effective intercalation and exfoliation of silicate layers. The homogeneously dispersed silicate platelets in the polymer matrices were confirmed by X-ray diffraction and transmission electron microscope analyses. An important contributor to this phenomenon must be the particular interaction between a small amount of MMA-units and silicate surfaces. This approach allows the nanocomposites with accompanying intercalation and exfoliation of silicate layers to be applied to a wide range of vaporizable monomers which in the absence of this technique would be otherwise difficult to individually prepare.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_21_link_62":{"attribute_name":"研究者情報","attribute_value_mlt":[{"subitem_link_url":"https://hyokadb02.jimu.kyutech.ac.jp/html/397_ja.html"}]},"item_21_publisher_7":{"attribute_name":"出版社","attribute_value_mlt":[{"subitem_publisher":"American Chemical Society","subitem_publisher_language":"en"}]},"item_21_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1021/ma901357p","subitem_relation_type_select":"DOI"}}]},"item_21_rights_13":{"attribute_name":"著作権関連情報","attribute_value_mlt":[{"subitem_rights":"Copyright (c) 2009 American Chemical Society"}]},"item_21_select_59":{"attribute_name":"査読の有無","attribute_value_mlt":[{"subitem_select_item":"yes"}]},"item_21_source_id_10":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AA0071963X","subitem_source_identifier_type":"NCID"}]},"item_21_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1520-5835","subitem_source_identifier_type":"EISSN"},{"subitem_source_identifier":"0024-9297","subitem_source_identifier_type":"PISSN"}]},"item_21_text_28":{"attribute_name":"論文ID（連携）","attribute_value_mlt":[{"subitem_text_value":"10219050"}]},"item_21_text_63":{"attribute_name":"連携ID","attribute_value_mlt":[{"subitem_text_value":"6964"}]},"item_21_version_type_58":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNames":[{}]}],"creatorNames":[{"creatorName":"Ando, Yoshito","creatorNameLang":"en"},{"creatorName":"安藤, 義人","creatorNameLang":"ja"},{"creatorName":"アンドウ, ヨシト","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{},{},{},{}]},{"creatorNames":[{"creatorName":"Jeong, Jae-Mun","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorAffiliations":[{"affiliationNames":[{}]}],"creatorNames":[{"creatorName":"Nishida, Haruo","creatorNameLang":"en"},{"creatorName":"西田, 治男","creatorNameLang":"ja"},{"creatorName":"ニシダ, ハルオ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{},{},{}]},{"creatorAffiliations":[{"affiliationNames":[{}]}],"creatorNames":[{"creatorName":"Endo, Takeshi","creatorNameLang":"en"},{"creatorName":"遠藤, 剛","creatorNameLang":"ja"},{"creatorName":"エンドウ, タケシ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-05-08"}],"displaytype":"detail","filename":"10219050.pdf","filesize":[{"value":"2.1 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"10219050.pdf","url":"https://kyutech.repo.nii.ac.jp/record/5527/files/10219050.pdf"},"version_id":"45e23efc-1e53-48d6-9e55-0ad84169582e"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"exfoliation","subitem_subject_scheme":"Other"},{"subitem_subject":"nanocomposite","subitem_subject_scheme":"Other"},{"subitem_subject":"organoclay","subitem_subject_scheme":"Other"},{"subitem_subject":"radical polymerization","subitem_subject_scheme":"Other"},{"subitem_subject":"vapor-phase assisted surface polymerization","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Simple Procedure for Polystyrene-based Nanocomposite Preparation by Vapor-Phase Assisted Surface Polymerization","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Simple Procedure for Polystyrene-based Nanocomposite Preparation by Vapor-Phase Assisted Surface Polymerization","subitem_title_language":"en"}]},"item_type_id":"21","owner":"3","path":["24"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2018-05-08"},"publish_date":"2018-05-08","publish_status":"0","recid":"5527","relation_version_is_last":true,"title":["Simple Procedure for Polystyrene-based Nanocomposite Preparation by Vapor-Phase Assisted Surface Polymerization"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2024-02-21T01:44:45.191978+00:00"}