@article{oai:kyutech.repo.nii.ac.jp:00005547,
 author = {Fan,  Yujiang and Nishida, Haruo and 西田, 治男 and Mori,  Tomokazu and Shirai, Yoshihito and 白井, 義人 and Endo, Takeshi and 遠藤, 剛},
 issue = {4},
 journal = {Polymer},
 month = {Jan},
 note = {To achieve the feed stock recycling of poly(L-lactide) (PLLA) to L,L-lactide, PLLA composites including alkali earth metal oxides, such as calcium oxide (CaO) and magnesium oxide (MgO), were prepared and the effect of such metal oxides on the thermal degradation was investigated from the viewpoint of selective L,L-lactide formation. Metal oxides both lowered the degradation temperature range of PLLA and completely suppressed the production of oligomers other than lactides. CaO markedly lowered the degradation temperature, but caused some racemization of lactide, especially in a temperature range lower than 250 °C. Interestingly, with MgO racemization was avoided even in the lower temperature range. It is considered that the effect of MgO on the racemization is due to the lower basicity of Mg compared to Ca. At temperatures lower than 270 °C, the pyrolysis of PLLA/MgO (5 wt%) composite occurred smoothly causing unzipping depolymerization, resulting in selective L,L-lactide production. A degradation mechanism was discussed based on the results of kinetic analysis. A practical approach for the selective production of L,L-lactide from PLLA is proposed by using the PLLA/MgO composite.},
 pages = {1197--1205},
 title = {Thermal degradation of poly(L-lactide): effect of alkali earth metal oxides for selective L,L-lactide formation},
 volume = {45},
 year = {2004},
 yomi = {ニシダ, ハルオ and シライ, ヨシヒト and エンドウ, タケシ}
}