{"created":"2023-05-15T11:59:24.822711+00:00","id":5813,"links":{},"metadata":{"_buckets":{"deposit":"51dc082e-1959-4db9-ac4e-2da902a352bf"},"_deposit":{"created_by":3,"id":"5813","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"5813"},"status":"published"},"_oai":{"id":"oai:kyutech.repo.nii.ac.jp:00005813","sets":["8:9"]},"author_link":["23707","23704","23705","23702","6794","23703","23706"],"item_21_alternative_title_18":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Development of visible light response of CeO2-x with a high content of Ce3+ and its photocatalytic property"}]},"item_21_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-12-11","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"6","bibliographicPageEnd":"1271","bibliographicPageStart":"1267","bibliographicVolumeNumber":"10","bibliographic_titles":[{"bibliographic_title":"ChemCatChem"}]}]},"item_21_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Photocatalysts that are responsive to visible light are necessary to utilize solar energy. We prepared reduced CeO2−x with absorption in the visible region by a simple solvothermal method. A new absorption band appearing at λ≈500 nm (surface plasmon resonance) could be ascribed to the high content of Ce3+. To elucidate the relationship between Ce3+ and activity, the decomposition of isopropyl alcohol (IPA) to generate acetone was performed under visible‐light irradiation. CeO2−x showed activity that was superior to that of pure CeO2. Ce3+ induced oxygen vacancies in the lattice of CeO2−x, and this resulted in an improvement in the activity. In addition, the introduction of Ce3+ resulted in an improvement in the absorption of CeO2−x in the visible‐light region. Also, the appearance of small tentacles (Confeito‐like) on the surface of CeO2−x not only provided more active sites but also prevented aggregation. Owing to its visible‐light responsiveness and unique morphology, the performance of this material was significantly improved relative to that of pure CeO2.","subitem_description_type":"Abstract"}]},"item_21_description_60":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Journal Article","subitem_description_type":"Other"}]},"item_21_link_62":{"attribute_name":"研究者情報","attribute_value_mlt":[{"subitem_link_url":"https://hyokadb02.jimu.kyutech.ac.jp/html/98_ja.html"}]},"item_21_publisher_7":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley-V C H Verlag GMBH"}]},"item_21_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"info:doi/10.1002/cctc.201701767","subitem_relation_type_select":"DOI"}}]},"item_21_relation_14":{"attribute_name":"情報源","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://doi.org/10.1002/cctc.201701767"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/cctc.201701767","subitem_relation_type_select":"DOI"}}]},"item_21_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright (c) 2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim"}]},"item_21_select_59":{"attribute_name":"査読の有無","attribute_value_mlt":[{"subitem_select_item":"yes"}]},"item_21_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA12433532","subitem_source_identifier_type":"NCID"}]},"item_21_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1867-3880","subitem_source_identifier_type":"ISSN"},{"subitem_source_identifier":"1867-3899","subitem_source_identifier_type":"ISSN"}]},"item_21_subject_16":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"425","subitem_subject_scheme":"NDC"}]},"item_21_text_28":{"attribute_name":"論文ID（連携）","attribute_value_mlt":[{"subitem_text_value":"10316613"}]},"item_21_text_36":{"attribute_name":"著者所属","attribute_value_mlt":[{"subitem_text_value":"School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, P.R. China"},{"subitem_text_value":"School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, P.R. China"},{"subitem_text_value":"School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, P.R. China"},{"subitem_text_value":"School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, P.R. China"},{"subitem_text_value":"School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, P.R. China"},{"subitem_text_value":"School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, P.R. China"},{"subitem_text_value":"Department of Applied Chemistry, Kyushu Institute of Technology, Kitakyushu, Japan"}]},"item_21_text_63":{"attribute_name":"連携ID","attribute_value_mlt":[{"subitem_text_value":"6933"}]},"item_21_version_type_58":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Yuán,  Sàisài"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Xu,  Bin"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Zhang,  Qitao"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Liu,  Sixiao"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Xie,  Ju"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Zhang,  Ming"}],"nameIdentifiers":[{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"Ohno, Teruhisa","creatorNameLang":"en"},{"creatorName":"横野, 照尚","creatorNameLang":"ja"},{"creatorName":"オウノ, テルヒサ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{},{},{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-02-15"}],"displaytype":"detail","filename":"cctc.201701767.pdf","filesize":[{"value":"564.5 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"cctc.201701767.pdf","url":"https://kyutech.repo.nii.ac.jp/record/5813/files/cctc.201701767.pdf"},"version_id":"a430e5d4-7706-4e53-8bb3-08615e51330d"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"cerium","subitem_subject_scheme":"Other"},{"subitem_subject":"energy conversion","subitem_subject_scheme":"Other"},{"subitem_subject":"photocatalysis","subitem_subject_scheme":"Other"},{"subitem_subject":"surface plasmon resonance","subitem_subject_scheme":"Other"},{"subitem_subject":"visible light response","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Development of the Visible‐Light Response of CeO2−x with a high Ce3+ Content and Its Photocatalytic Properties","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Development of the Visible‐Light Response of CeO2−x with a high Ce3+ Content and Its Photocatalytic Properties"}]},"item_type_id":"21","owner":"3","path":["9"],"pubdate":{"attribute_name":"公開日","attribute_value":"2019-02-15"},"publish_date":"2019-02-15","publish_status":"0","recid":"5813","relation_version_is_last":true,"title":["Development of the Visible‐Light Response of CeO2−x with a high Ce3+ Content and Its Photocatalytic Properties"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2024-04-02T08:34:04.789771+00:00"}