@article{oai:kyutech.repo.nii.ac.jp:00005916,
 author = {Yang, Fu and Kapil, Gaurav and Zhang, Putao and Hu, Zhaosheng and Kamarudin, Muhammad Akmal and Ma, Tingli and 馬, 廷麗 and Hayase, Shuzi and 早瀬, 修二},
 issue = {19},
 journal = {ACS Applied Materials & Interfaces},
 month = {May},
 note = {High-efficiency perovskite solar cells (PSCs) need to be fabricated in the nitrogen-filled glovebox by the atmosphere-controlled crystallization process. However, the use of the glovebox process is of great concern for mass level production of PSCs. In this work, notable efficient CH3NH3PbI3 solar cells can be obtained in high humidity ambient atmosphere (60–70% relative humidity) by using acetate as the antisolvent, in which dependence of methyl, ethyl, propyl, and butyl acetate on the crystal growth mechanism is discussed. It is explored that acetate screens the sensitive perovskite intermediate phases from water molecules during perovskite film formation and annealing. It is revealed that relatively high vapor pressure and high water solubility of methyl acetate (MA) leads to the formation of highly dense and pinhole free perovskite films guiding to the best power conversion efficiency (PCE) of 16.3% with a reduced hysteresis. The devices prepared using MA showed remarkable shelf life stability of more than 80% for 360 h in ambient air condition, when compared to the devices fabricated using other antisolvents with low vapor pressure and low water solubility. Moreover, the PCE was still kept at 15.6% even though 2 vol % deionized water was added in the MA for preparing the perovskite layer.},
 pages = {16482--16489},
 title = {Dependence of acetate based anti-solvent for high humidity fabrication of CH3NH3PbI3 perovskite devices in ambient atmosphere},
 volume = {10},
 year = {2018},
 yomi = {マ, テイレイ and ハヤセ, シュウジ}
}