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Vapor-Phase Growth and Structural Characterization of Single Crystals of Magnesium Doped Two-Dimensional Fullerene Polymer Mg2C60
http://hdl.handle.net/10228/00007153
http://hdl.handle.net/10228/000071532cc442c4-4b30-41a8-bd73-88acdb245f4a
| 名前 / ファイル | ライセンス | アクション |
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acs.cgd.8b00186.pdf (664.7 kB)
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| アイテムタイプ | 学術雑誌論文 = Journal Article(1) | |||||||||||||
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| 公開日 | 2019-06-10 | |||||||||||||
| 資源タイプ | ||||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||||
| 資源タイプ | journal article | |||||||||||||
| タイトル | ||||||||||||||
| タイトル | Vapor-Phase Growth and Structural Characterization of Single Crystals of Magnesium Doped Two-Dimensional Fullerene Polymer Mg2C60 | |||||||||||||
| 言語 | en | |||||||||||||
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| 言語 | eng | |||||||||||||
| 著者 |
田中, 将嗣
× 田中, 将嗣
WEKO
22595
× Yamanaka, Shoji |
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| 抄録 | ||||||||||||||
| 内容記述タイプ | Abstract | |||||||||||||
| 内容記述 | Single crystals of magnesium doped fullerene polymer Mg2C60 can be directly grown via a binary vapor-phase mixture of Mg and C60, in sealed glass tubes at elevated temperatures. This is the first single crystal, in metal-doped two-dimensional fullerene polymers, which enables precise X-ray structural refinement. The Mg2C60 crystallizes in a monoclinic space group, I2/m, with lattice parameters of a = 9.324(2) Å, b = 9.041(2) Å, c = 14.817(3) Å, and β = 91.699(10)°. A Mg atom is located at each tetrahedral fullerene ball interstice, where the shortest Mg–C distance is 2.341(2) Å, suggesting that the Mg cation is in van der Waals contact with carbon p orbitals. The precise structure of the two-dimensional fullerene polymer network is characterized by comparison with structural data reported previously on powder samples. | |||||||||||||
| 書誌情報 |
Crystal Growth & Design 巻 18, 号 7, p. 3877-3882, 発行日 2018-06-04 |
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| 出版者 | American Chemical Society | |||||||||||||
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| 関連タイプ | isIdenticalTo | |||||||||||||
| 識別子タイプ | DOI | |||||||||||||
| 関連識別子 | https://doi.org/10.1021/acs.cgd.8b00186 | |||||||||||||
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| 収録物識別子タイプ | NCID | |||||||||||||
| 収録物識別子 | AA1150352X | |||||||||||||
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| 収録物識別子タイプ | PISSN | |||||||||||||
| 収録物識別子 | 1528-7483 | |||||||||||||
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| 収録物識別子タイプ | EISSN | |||||||||||||
| 収録物識別子 | 1528-7505 | |||||||||||||
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| 権利情報 | Copyright (c) 2018 American Chemical Society. This material is excerpted from a work that was published in Crystal Growth & Design, copyright © American Chemical Society after peer review. | |||||||||||||
| 出版タイプ | ||||||||||||||
| 出版タイプ | AM | |||||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||||||||||
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| 値 | yes | |||||||||||||
| 研究者情報 | ||||||||||||||
| URL | https://hyokadb02.jimu.kyutech.ac.jp/html/100001006_ja.html | |||||||||||||
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| 値 | 10320410 | |||||||||||||
| 連携ID | ||||||||||||||
| 値 | 7158 | |||||||||||||
