@article{oai:kyutech.repo.nii.ac.jp:00006096, author = {Yang, Fu and Hirotani, Daisuke and Kapil, Gaurav and Kamarudin, Muhammad Akmal and Ng, Chi Huey and Zhang, Yaohong and Shen, Qing and Hayase, Shuzi and 早瀬, 修二}, issue = {39}, journal = {Angewandte Chemie International edition}, month = {Aug}, note = {01 August Compared with organic‐inorganic perovskites, all‐inorganic cesium‐based perovskites without volatile organic compounds have gained extensive interests because of the high thermal stability. However, they have a problem on phase transition from cubic phase (active for photo‐electric conversion) to orthorhombic phase (inactive for photo‐electric conversion) at room temperature, which has hindered further progress. Herein, novel inorganic CsPb1−xGexI2Br perovskites were prepared in humid ambient atmosphere without a glovebox. The phase stability of the all‐inorganic perovskite was effectively enhanced after germanium addition. In addition, the highest power conversion efficiency of 10.8 % with high open‐circuit voltage (VOC) of 1.27 V in a planar solar cell based on CsPb0.8Ge0.2I2Br perovskite was achieved. Furthermore, the highest VOC up to 1.34 V was obtained by CsPb0.7Ge0.3I2Br perovskite, which is a remarkable record in the field of all‐inorganic perovskite solar cells. More importantly, all the photovoltaic parameters of CsPb0.8Ge0.2I2Br perovskite solar cells showed nearly no decay after 7 h measurement in 50–60 % relative humidity without encapsulation.}, pages = {12745--12749}, title = {All‐Inorganic CsPb1−xGexI2Br Perovskite with Enhanced Phase Stability and Photovoltaic Performance}, volume = {57}, year = {2018}, yomi = {ハヤセ, シュウジ} }