@article{oai:kyutech.repo.nii.ac.jp:00006105, author = {Zhang, Putao and Yang, Fu and Kamarudin, Muhammad Akmal and Ng, Chi Huey and Kapil, Gaurav and Ma, Tingli and 馬, 廷麗 and Hayase, Shuzi and 早瀬, 修二}, issue = {35}, journal = {ACS Applied Materials & Interfaces}, month = {Aug}, note = {TiO2 is commonly used as an electron-transporting material in perovskite photovoltaic devices due to its advantages, including suitable band gap, good photoelectrochemical stability, and simple preparation process. However, there are many oxygen vacancies or defects on the surface of TiO2 and thus this affects the stability of TiO2-based perovskite solar cells under UV light. In this work, a thin (monolayer) SbI3 modification layer is introduced on the mesoporous TiO2 surface and the effect at the interface between of TiO2 and perovskite is monitored by using a quartz crystal microbalance system. We demonstrate that the SbI3-modified TiO2 electrodes exhibit superior electronic properties by reducing electronic trap states, enabling faster electron transport. This approach results in higher performances compared with electrodes without the SbI3 passivation layer. CH3NH3PbI3 perovskite solar cells with a maximum power conversion efficiency of 17.33% in air, accompanied by a reduction in hysteresis and enhancement of the device stability, are reported.}, pages = {29630--29637}, title = {Performance Enhancement of Mesoporous TiO2-Based Perovskite Solar Cells by SbI3 Interfacial Modification Layer}, volume = {10}, year = {2018}, yomi = {マ, テイレイ and ハヤセ, シュウジ} }