{"created":"2023-05-15T11:59:58.957802+00:00","id":6631,"links":{},"metadata":{"_buckets":{"deposit":"ab0ac106-1669-41f4-9d05-64251e341015"},"_deposit":{"created_by":3,"id":"6631","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"6631"},"status":"published"},"_oai":{"id":"oai:kyutech.repo.nii.ac.jp:00006631","sets":["8:9"]},"author_link":["28027","22006","28026"],"item_21_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2019-08-05","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"16","bibliographicPageEnd":"6087","bibliographicPageStart":"6080","bibliographicVolumeNumber":"52","bibliographic_titles":[{"bibliographic_title":"Macromolecules"}]}]},"item_21_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Aliphatic polydithiourethanes (PDTUs) were successfully synthesized from diisothiocyanates and dithiols having different values of the carbon atom number. The thermal properties and hydrogen-bonding behavior of PDTUs were studied in detail by using differential scanning calorimetry, thermal gravimetric analysis, temperature dependence nuclear magnetic resonance, Fourier transform infrared-attenuated total reflection, and density functional theory and semiempirical molecular orbital methods. In this work, we demonstrated that the thermal decomposition of PDTUs happened from the cleavage of the C–S bond of the dithiocarbamate moiety in the main chain and also that the active isothiocyanate and thiol groups were reprepared in the terminal of the decomposed polymer (i.e., oligomer). Furthermore, we found that the thermal depolymerization of PDTUs and the repolymerization of dithiourethane oligomers at room temperature proceeded repeatedly a few times.","subitem_description_type":"Abstract"}]},"item_21_description_60":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Journal Article","subitem_description_type":"Other"}]},"item_21_publisher_7":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"American Chemical Society"}]},"item_21_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1021/acs.macromol.9b00350","subitem_relation_type_select":"DOI"}}]},"item_21_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright (c) ACM, 2019. This is the author's version of the work. It is posted here by permission of ACM for your personal use. Not for redistribution. The definitive version was published in Macromolecules, 2019, 52, 16, 6080–6087 https://doi.org/10.1021/acs.macromol.9b00350"}]},"item_21_select_59":{"attribute_name":"査読の有無","attribute_value_mlt":[{"subitem_select_item":"yes"}]},"item_21_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA0071963X","subitem_source_identifier_type":"NCID"}]},"item_21_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0024-9297","subitem_source_identifier_type":"ISSN"},{"subitem_source_identifier":"1520-5835","subitem_source_identifier_type":"ISSN"}]},"item_21_text_36":{"attribute_name":"著者所属","attribute_value_mlt":[{"subitem_text_value":"Molecular Engineering Institute, Kyushu Institute of Technology, 1-1 Sensui-cho, Tobata-ku, Kitakyushu-shi, Fukuoka 804-8550, Japan"},{"subitem_text_value":"Materials Science Institute, Konishi Co., Ltd., 5-3-35 Nishibori, Sakura-ku, Saitama, Saitama 338-0832, Japan"},{"subitem_text_value":"Molecular Engineering Institute, Kyushu Institute of Technology, 1-1 Sensui-cho, Tobata-ku, Kitakyushu-shi, Fukuoka 804-8550, Japan"}]},"item_21_text_63":{"attribute_name":"連携ID","attribute_value_mlt":[{"subitem_text_value":"7946"}]},"item_21_version_type_58":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"Yoshida, Yoshiaki","creatorNameLang":"en"},{"creatorName":"吉田, 嘉晃","creatorNameLang":"ja"},{"creatorName":"ヨシダ, ヨシアキ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{},{},{}]},{"creatorNames":[{"creatorName":"Ohnaka,  Kenji"}],"nameIdentifiers":[{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"Endo, Takeshi","creatorNameLang":"en"},{"creatorName":"遠藤, 剛","creatorNameLang":"ja"},{"creatorName":"エンドウ, タケシ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-08-05"}],"displaytype":"detail","filename":"MEI_2019-04.pdf","filesize":[{"value":"783.0 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"MEI_2019-04.pdf","url":"https://kyutech.repo.nii.ac.jp/record/6631/files/MEI_2019-04.pdf"},"version_id":"a2d00404-2b98-471e-b1f8-3e703e568a9c"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Reprocessable Aliphatic Polydithiourethanes Based on the Reversible Addition Reaction of Diisothiocyanates and Dithiols","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Reprocessable Aliphatic Polydithiourethanes Based on the Reversible Addition Reaction of Diisothiocyanates and Dithiols"}]},"item_type_id":"21","owner":"3","path":["9"],"pubdate":{"attribute_name":"公開日","attribute_value":"2020-08-05"},"publish_date":"2020-08-05","publish_status":"0","recid":"6631","relation_version_is_last":true,"title":["Reprocessable Aliphatic Polydithiourethanes Based on the Reversible Addition Reaction of Diisothiocyanates and Dithiols"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2024-04-02T08:45:32.763059+00:00"}