{"created":"2023-05-15T12:00:02.583039+00:00","id":6703,"links":{},"metadata":{"_buckets":{"deposit":"c3be2c1a-ac4f-4122-b6f0-c354e692adba"},"_deposit":{"created_by":3,"id":"6703","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"6703"},"status":"published"},"_oai":{"id":"oai:kyutech.repo.nii.ac.jp:00006703","sets":["8:9"]},"author_link":["22006","28026","28370"],"item_21_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2019-09-30","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"20","bibliographicPageEnd":"2137","bibliographicPageStart":"2131","bibliographicVolumeNumber":"57","bibliographic_titles":[{"bibliographic_title":"Journal of Polymer Science Part A: Polymer Chemistry"}]}]},"item_21_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"We have already found that the polymers, which are obtained by the polymerization of 4‐vinylphenyl isothoiocyanate after the zwitterion formation with cyclic amidines, are networked through the ionic interaction among the zwitterions becoming insoluble to various solvents. We report here on the results of the reaction of nucleophilic reagents such as amines and alcohols with the zwitterionic adduct to investigate about the decrosslinking through the resolution of ionic interactions. In the model reactions of amines and alcohols with the zwitterion compounds, which were consisted of the phenyl isothiocyanate and cyclic amidines, the reaction of nucleophilic reagents and zwitterionic adducts having methyl group at the 2‐position of the amidine proceed quantitatively. Based on the model reaction, such nucleophilic addition was applicable to decrosslinking reaction of the networked polymers containing the zwitterion structure in the side‐chain.","subitem_description_type":"Abstract"}]},"item_21_description_60":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Journal Article","subitem_description_type":"Other"}]},"item_21_publisher_7":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley Periodicals, Inc."}]},"item_21_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/pola.29485","subitem_relation_type_select":"DOI"}}]},"item_21_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright (c) 2019 Wiley Periodicals, Inc."}]},"item_21_select_59":{"attribute_name":"査読の有無","attribute_value_mlt":[{"subitem_select_item":"yes"}]},"item_21_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA11624127","subitem_source_identifier_type":"NCID"}]},"item_21_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1099-0518","subitem_source_identifier_type":"ISSN"}]},"item_21_subject_16":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"431","subitem_subject_scheme":"NDC"}]},"item_21_text_36":{"attribute_name":"著者所属","attribute_value_mlt":[{"subitem_text_value":"Molecular Engineering Institute, Kyushu Institute of Technology, 1-1 Sensui-cho, Tobata-ku, Kitakyushu-shi, Fukuoka 804-8550, Japan"},{"subitem_text_value":"Molecular Engineering Institute, Kyushu Institute of Technology, 1-1 Sensui-cho, Tobata-ku, Kitakyushu-shi, Fukuoka 804-8550, Japan"},{"subitem_text_value":"Molecular Engineering Institute, Kyushu Institute of Technology, 1-1 Sensui-cho, Tobata-ku, Kitakyushu-shi, Fukuoka 804-8550, Japan"}]},"item_21_text_63":{"attribute_name":"連携ID","attribute_value_mlt":[{"subitem_text_value":"7940"}]},"item_21_version_type_58":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Yamauchi,  Akira"}],"nameIdentifiers":[{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"Yoshida, Yoshiaki","creatorNameLang":"en"},{"creatorName":"吉田, 嘉晃","creatorNameLang":"ja"},{"creatorName":"ヨシダ, ヨシアキ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{},{},{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"Endo, Takeshi","creatorNameLang":"en"},{"creatorName":"遠藤, 剛","creatorNameLang":"ja"},{"creatorName":"エンドウ, タケシ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-09-30"}],"displaytype":"detail","filename":"MEI_2019-03.pdf","filesize":[{"value":"2.4 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"MEI_2019-03.pdf","url":"https://kyutech.repo.nii.ac.jp/record/6703/files/MEI_2019-03.pdf"},"version_id":"89fc6679-d365-42b1-b940-451de561ec20"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"zwitterion structure","subitem_subject_scheme":"Other"},{"subitem_subject":"decrosslinking reaction","subitem_subject_scheme":"Other"},{"subitem_subject":"polymer reaction","subitem_subject_scheme":"Other"},{"subitem_subject":"radical polymerization","subitem_subject_scheme":"Other"},{"subitem_subject":"copolymer","subitem_subject_scheme":"Other"},{"subitem_subject":"zwitterion adduct","subitem_subject_scheme":"Other"},{"subitem_subject":"crosslinking","subitem_subject_scheme":"Other"},{"subitem_subject":"decrosslinking","subitem_subject_scheme":"Other"},{"subitem_subject":"thiourea","subitem_subject_scheme":"Other"},{"subitem_subject":"thiourethane","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthesis and decrosslinking of networked polymers having zwitterion structure consisted by cyclic amidine and isothiocyanate","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Synthesis and decrosslinking of networked polymers having zwitterion structure consisted by cyclic amidine and isothiocyanate"}]},"item_type_id":"21","owner":"3","path":["9"],"pubdate":{"attribute_name":"公開日","attribute_value":"2020-09-30"},"publish_date":"2020-09-30","publish_status":"0","recid":"6703","relation_version_is_last":true,"title":["Synthesis and decrosslinking of networked polymers having zwitterion structure consisted by cyclic amidine and isothiocyanate"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2024-04-02T08:39:37.006736+00:00"}