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Ordered arrangement of F4TCNQ anions in three-dimensionally oriented P3HT thin films
http://hdl.handle.net/10228/00007973
http://hdl.handle.net/10228/00007973559a6d3c-5fde-494a-9794-dbe1ff640ca3
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
iENERON-2020_49.pdf (2.1 MB)
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| Item type | 学術雑誌論文 = Journal Article(1) | |||||||||||||||||||
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| 公開日 | 2020-11-20 | |||||||||||||||||||
| 資源タイプ | ||||||||||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||||||||||
| 資源タイプ | journal article | |||||||||||||||||||
| タイトル | ||||||||||||||||||||
| タイトル | Ordered arrangement of F4TCNQ anions in three-dimensionally oriented P3HT thin films | |||||||||||||||||||
| 言語 | en | |||||||||||||||||||
| 言語 | ||||||||||||||||||||
| 言語 | eng | |||||||||||||||||||
| 著者 |
永松, 秀一
× 永松, 秀一
WEKO
1670
× パンディ, シャム スディル
WEKO
6311
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| 抄録 | ||||||||||||||||||||
| 内容記述タイプ | Abstract | |||||||||||||||||||
| 内容記述 | An ordered arrangement of electron-accepting molecular dopant, 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane (F4TCNQ), in three-dimensionally (3D) oriented poly(3-hexylthiophene) (P3HT) film was clarified. The 3D oriented P3HT thin films prepared by the friction-transfer technique were doped with F4TCNQ by dipping into an acetonitrile solution. The presence of F4TCNQ anions in the 3D oriented P3HT thin films was investigated by polarized ultraviolet/visible/near-infrared absorption spectroscopy, grazing incidence X-ray diffractometry, polarized Fourier transform infrared spectroscopy (FT-IR), and infrared p-polarized multiple-angle incidence resolution spectroscopy (pMAIRS). The F4TCNQ-doped 3D oriented P3HT films showed anisotropic properties in all characterizations. In particular, the anisotropic molecular vibrations from polarized FT-IR and pMAIRS have clearly revealed orientations of polymeric chains and molecular dopant molecules. Considering the results from several independent techniques indicated that F4TCNQ anions in the 3D oriented P3HT were orderly arranged in a 3D manner with respect to the 3D oriented P3HT such that their molecular long-axis parallel to the P3HT backbone, with in-plane molecular orientation. Additionally, the direction of the optical transition moment of the F4TCNQ anion was found to be parallel to the molecular short-axis. | |||||||||||||||||||
| 書誌情報 |
Scientific Reports 巻 10, p. 20020-1-20020-10, 発行日 2020-11-18 |
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| 出版社 | ||||||||||||||||||||
| 出版者 | Nature Publishing Group | |||||||||||||||||||
| DOI | ||||||||||||||||||||
| 関連タイプ | isIdenticalTo | |||||||||||||||||||
| 識別子タイプ | DOI | |||||||||||||||||||
| 関連識別子 | https://doi.org/10.1038/s41598-020-77022-0 | |||||||||||||||||||
| 日本十進分類法 | ||||||||||||||||||||
| 主題Scheme | NDC | |||||||||||||||||||
| 主題 | 428 | |||||||||||||||||||
| ISSN | ||||||||||||||||||||
| 収録物識別子タイプ | ISSN | |||||||||||||||||||
| 収録物識別子 | 2045-2322 | |||||||||||||||||||
| 著作権関連情報 | ||||||||||||||||||||
| 権利情報Resource | http://creativecommons.org/licenses/by/4.0/ | |||||||||||||||||||
| 権利情報 | Copyright (c) The Author(s) 2020. Creative Commons Attribution 4.0 | |||||||||||||||||||
| キーワード | ||||||||||||||||||||
| 主題Scheme | Other | |||||||||||||||||||
| 主題 | Materials for devices | |||||||||||||||||||
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| 主題Scheme | Other | |||||||||||||||||||
| 主題 | Materials science | |||||||||||||||||||
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| 主題Scheme | Other | |||||||||||||||||||
| 主題 | Soft materials | |||||||||||||||||||
| 出版タイプ | ||||||||||||||||||||
| 出版タイプ | VoR | |||||||||||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||||||||||||
| 査読の有無 | ||||||||||||||||||||
| 値 | yes | |||||||||||||||||||
| 研究者情報 | ||||||||||||||||||||
| URL | https://hyokadb02.jimu.kyutech.ac.jp/html/217_ja.html | |||||||||||||||||||
| 論文ID（連携） | ||||||||||||||||||||
| 値 | 10360098 | |||||||||||||||||||
| 連携ID | ||||||||||||||||||||
| 値 | 8495 | |||||||||||||||||||
