@article{oai:kyutech.repo.nii.ac.jp:00006775, author = {Nagao, Masanori and Tanaka, Masashi and 田中, 将嗣 and Miura, Akira and Kitamura, Miho and Horiba, Koji and Watauchi, Satoshi and Takano, Yoshihiko and Kumigashira, Hiroshi and Tanaka, Isao}, journal = {Solid State Communications}, month = {Dec}, note = {Ce(O,F)Sb(S,Se)2 single crystals were successfully grown using a CsCl/KCl flux method. The obtained crystals have a plate-like shape with the typical size of 1–2mm and well-developed ab-plane, which enables X-ray single crystal structural analysis. The Ce(O,F)Sb(S,Se)2 crystallizes in a monoclinic space group, P21/m, with lattice parameters of a=4.121(7) Å, b=4.109(7) Å, c=13.233(15) Å, β=97.94(7) °. It is composed of alternate stacking of Ce-(O,F) and Sb-SSe layers, and the Sb-SSe layer includes selective occupation of Se atoms in its in-plane site. The valence state of Ce is estimated to be Ce3+ by X-ray absorption fine spectroscopy analysis. The single crystals show an insulating behavior, and a magnetic ordering around 6K.}, pages = {38--42}, title = {Growth and physical properties of Ce(O,F)Sb(S,Se)2 single crystals with site-selected chalcogen atoms}, volume = {289}, year = {2018}, yomi = {タナカ, マサシ} }