{"created":"2023-05-15T12:00:08.991352+00:00","id":6844,"links":{},"metadata":{"_buckets":{"deposit":"0b1fed96-17c5-49a6-8f78-02ea281a2beb"},"_deposit":{"created_by":3,"id":"6844","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"6844"},"status":"published"},"_oai":{"id":"oai:kyutech.repo.nii.ac.jp:00006844","sets":["8:24"]},"author_link":["29152","29144","29141","29149","29142","29143","29151","29148","29145","6794","29150","29153","29146"],"item_21_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020-03-09","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"9","bibliographicPageEnd":"2646","bibliographicPageStart":"2638","bibliographicVolumeNumber":"12","bibliographic_titles":[{"bibliographic_title":"ChemCatChem"}]}]},"item_21_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"CeO2 doped with various rare earth (RE) ions (Sm, Y, La and Nd) having a broom‐like hierarchical structure was successfully prepared by a template‐free hydrothermal method. The photooxidation performance of RE‐doped products was significantly better than that of pure CeO2, and comparative experiments showed that Sm‐doped CeO2 (SC) has superior photooxidation activity, resulting about 3.0‐times and 8.5‐times higher activities of bisphenol A (BPA) degradation and of acetaldehyde (CH3CHO) decomposition, respectively, than those of pure CeO2. Due to the incorporation of RE ions, the surface exposed cerium ions are partly substituted by those cations, resulting in a higher concentration of oxygen vacancies (Ov) in RE‐doped CeO2. The increased Ov can act as a trapping center for photo‐generated electrons to form a doping transition state between the conduction band (CB) and valence band (VB), which can restrict the recombination rate of electrons and holes effectively and lead to an outstanding enhancement of photooxidation performance. Furthermore, abundant highly reactive hydroxyl radicals (.OH) and superoxide radicals (.O2−), which are efficient intermediates with vivid oxidation ability, can further enhance the photocatalytic activity of RE‐doped CeO2. A cost‐effective strategy for designing CeO2‐based semiconductor photocatalysts doped with multitudinous RE ions that have enhanced photooxidation performance is presented in this paper.","subitem_description_type":"Abstract"}]},"item_21_description_60":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Journal Article","subitem_description_type":"Other"}]},"item_21_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"29148","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Xu,  B."}]},{"nameIdentifiers":[{"nameIdentifier":"29149","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Yang,  H."}]},{"nameIdentifiers":[{"nameIdentifier":"29150","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Zhang,  Q."}]},{"nameIdentifiers":[{"nameIdentifier":"29151","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Yuan,  S."}]},{"nameIdentifiers":[{"nameIdentifier":"29152","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Xie,  A."}]},{"nameIdentifiers":[{"nameIdentifier":"29153","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Zhang,  M."}]},{"affiliations":[{"affiliationNames":[{"affiliationName":"","lang":"ja"}],"nameIdentifiers":[]}],"familyNames":[{"familyName":"Ohno","familyNameLang":"en"},{"familyName":"横野","familyNameLang":"ja"},{"familyName":"オウノ","familyNameLang":"ja-Kana"}],"givenNames":[{"givenName":"Teruhisa","givenNameLang":"en"},{"givenName":"照尚","givenNameLang":"ja"},{"givenName":"テルヒサ","givenNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"6794","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"10203887","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://nrid.nii.ac.jp/ja/nrid/1000010203887"},{"nameIdentifier":"7402659316","nameIdentifierScheme":"Scopus著者ID","nameIdentifierURI":"https://www.scopus.com/authid/detail.uri?authorId=7402659316"},{"nameIdentifier":"0000-0002-7825-8189","nameIdentifierScheme":"ORCiD","nameIdentifierURI":"https://orcid.org/0000-0002-7825-8189"},{"nameIdentifier":"98","nameIdentifierScheme":"九工大研究者情報","nameIdentifierURI":"https://hyokadb02.jimu.kyutech.ac.jp/html/98_ja.html"}],"names":[{"name":"Ohno, Teruhisa","nameLang":"en"},{"name":"横野, 照尚","nameLang":"ja"},{"name":"オウノ, テルヒサ","nameLang":"ja-Kana"}]}]},"item_21_link_62":{"attribute_name":"研究者情報","attribute_value_mlt":[{"subitem_link_url":"https://hyokadb02.jimu.kyutech.ac.jp/html/98_ja.html"}]},"item_21_publisher_7":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley‐VCH Verlag GmbH & Co. KGaA"}]},"item_21_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/cctc.201902309","subitem_relation_type_select":"DOI"}}]},"item_21_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright (c) 2020 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim"}]},"item_21_select_59":{"attribute_name":"査読の有無","attribute_value_mlt":[{"subitem_select_item":"yes"}]},"item_21_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1867-3899","subitem_source_identifier_type":"ISSN"}]},"item_21_subject_16":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"572","subitem_subject_scheme":"NDC"}]},"item_21_text_28":{"attribute_name":"論文ID（連携）","attribute_value_mlt":[{"subitem_text_value":"10358106"}]},"item_21_text_36":{"attribute_name":"著者所属","attribute_value_mlt":[{"subitem_text_value":"Yangzhou University"},{"subitem_text_value":"Yangzhou University"},{"subitem_text_value":"Shenzhen University"},{"subitem_text_value":"Xiamen University"},{"subitem_text_value":"Yangzhou University"},{"subitem_text_value":"Yangzhou University"},{"subitem_text_value":"Kyushu Institute of Technology"}]},"item_21_text_63":{"attribute_name":"連携ID","attribute_value_mlt":[{"subitem_text_value":"8355"}]},"item_21_version_type_58":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Xu,  Bin"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yang,  Hui"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Zhang,  Qitao"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yuan,  Saisai"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Xie,  An"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Zhang,  Ming"}],"nameIdentifiers":[{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"Ohno, Teruhisa","creatorNameLang":"en"},{"creatorName":"横野, 照尚","creatorNameLang":"ja"},{"creatorName":"オウノ, テルヒサ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{},{},{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2021-03-09"}],"displaytype":"detail","filename":"iENERON-2020_07.pdf","filesize":[{"value":"1.4 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"iENERON-2020_07.pdf","url":"https://kyutech.repo.nii.ac.jp/record/6844/files/iENERON-2020_07.pdf"},"version_id":"a0cbe712-a81a-42b5-8690-5d80d590e96f"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Doped Ceria","subitem_subject_scheme":"Other"},{"subitem_subject":"Hierarchical structure","subitem_subject_scheme":"Other"},{"subitem_subject":"Oxygen vacancies","subitem_subject_scheme":"Other"},{"subitem_subject":"Photooxidation","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Design and Synthesis of Sm, Y, La and Nd‐doped CeO2 with a broom‐like hierarchical structure: a photocatalyst with enhanced oxidation performance","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Design and Synthesis of Sm, Y, La and Nd‐doped CeO2 with a broom‐like hierarchical structure: a photocatalyst with enhanced oxidation performance"}]},"item_type_id":"21","owner":"3","path":["24"],"pubdate":{"attribute_name":"公開日","attribute_value":"2021-03-09"},"publish_date":"2021-03-09","publish_status":"0","recid":"6844","relation_version_is_last":true,"title":["Design and Synthesis of Sm, Y, La and Nd‐doped CeO2 with a broom‐like hierarchical structure: a photocatalyst with enhanced oxidation performance"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-10-25T07:52:04.895737+00:00"}