@article{oai:kyutech.repo.nii.ac.jp:00007291, author = {Kataoka, Noriyuki and Tanaka, Masashi and 田中, 将嗣 and Hosoda, Wataru and Taniguchi, Takumi and Fujimori, Shin-ichi and Wakita, Takanori and Muraoka, Yuji and Yokoya, Takayoshi}, issue = {3}, journal = {Journal of Physics: Condensed Matter}, month = {Oct}, note = {We have performed soft x-ray spectroscopy in order to study the photoirradiation time dependence of the valence band structure and chemical states of layered transition metal nitride chloride TiNCl. Under the soft x-ray irradiation, the intensities of the states near the Fermi level (EF) and the Ti3+ component increased, while the Cl 2p intensity decreased. Ti 2p–3d resonance photoemission spectroscopy confirmed a distinctive Fermi edge with Ti 3d character. These results indicate the photo-induced metallization originates from deintercalation due to Cl desorption, and thus provide a new carrier doping method that controls the conducting properties of TiNCl.}, title = {Soft x-ray irradiation induced metallization of layered TiNCl}, volume = {33}, year = {2020}, yomi = {タナカ, マサシ} }