{"created":"2023-05-15T12:00:31.560852+00:00","id":7358,"links":{},"metadata":{"_buckets":{"deposit":"fd0c7b01-1d42-4a3e-bfb3-dcc475e6c1b0"},"_deposit":{"created_by":3,"id":"7358","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"7358"},"status":"published"},"_oai":{"id":"oai:kyutech.repo.nii.ac.jp:00007358","sets":["8:9"]},"author_link":["31826","31832","31837","31822","31829","31834","31825","31830","31823","31839","31844","31840","31828","31843","31841","31842","6794","31824","31831","31838","31835","31836","31827"],"item_21_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2021-05-21","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"5","bibliographicPageEnd":"384","bibliographicPageStart":"374","bibliographicVolumeNumber":"4","bibliographic_titles":[{"bibliographic_title":"Nature Catalysis"}]}]},"item_21_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Artificial photosynthesis offers a promising strategy to produce hydrogen peroxide (H2O2)—an environmentally friendly oxidant and a clean fuel. However, the low activity and selectivity of the two-electron oxygen reduction reaction (ORR) in the photocatalytic process greatly restricts the H2O2 production efficiency. Here we show a robust antimony single-atom photocatalyst (Sb-SAPC, single Sb atoms dispersed on carbon nitride) for the synthesis of H2O2 in a simple water and oxygen mixture under visible light irradiation. An apparent quantum yield of 17.6% at 420 nm together with a solar-to-chemical conversion efficiency of 0.61% for H2O2 synthesis was achieved. On the basis of time-dependent density function theory calculations, isotopic experiments and advanced spectroscopic characterizations, the photocatalytic performance is ascribed to the notably promoted two-electron ORR by forming μ-peroxide at the Sb sites and highly concentrated holes at the neighbouring N atoms. The in situ generated O2 via water oxidation is rapidly consumed by ORR, leading to boosted overall reaction kinetics.","subitem_description_type":"Abstract"}]},"item_21_description_60":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Journal Article","subitem_description_type":"Other"}]},"item_21_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"31834","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Teng,  Z."}]},{"nameIdentifiers":[{"nameIdentifier":"31835","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Zhang,  Q."}]},{"nameIdentifiers":[{"nameIdentifier":"31836","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Yang,  H."}]},{"nameIdentifiers":[{"nameIdentifier":"31837","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Kato,  K."}]},{"nameIdentifiers":[{"nameIdentifier":"31838","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Yang,  W."}]},{"nameIdentifiers":[{"nameIdentifier":"31839","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Lu,  Y.R."}]},{"nameIdentifiers":[{"nameIdentifier":"31840","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Liu,  S."}]},{"nameIdentifiers":[{"nameIdentifier":"31841","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Wang,  C."}]},{"nameIdentifiers":[{"nameIdentifier":"31842","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Yamakata,  A."}]},{"nameIdentifiers":[{"nameIdentifier":"31843","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Su,  C."}]},{"nameIdentifiers":[{"nameIdentifier":"31844","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Liu,  B."}]},{"affiliations":[{"affiliationNames":[{"affiliationName":"","lang":"ja"}],"nameIdentifiers":[]}],"familyNames":[{"familyName":"Ohno","familyNameLang":"en"},{"familyName":"横野","familyNameLang":"ja"},{"familyName":"オウノ","familyNameLang":"ja-Kana"}],"givenNames":[{"givenName":"Teruhisa","givenNameLang":"en"},{"givenName":"照尚","givenNameLang":"ja"},{"givenName":"テルヒサ","givenNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"6794","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"10203887","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://nrid.nii.ac.jp/ja/nrid/1000010203887"},{"nameIdentifier":"7402659316","nameIdentifierScheme":"Scopus著者ID","nameIdentifierURI":"https://www.scopus.com/authid/detail.uri?authorId=7402659316"},{"nameIdentifier":"0000-0002-7825-8189","nameIdentifierScheme":"ORCiD","nameIdentifierURI":"https://orcid.org/0000-0002-7825-8189"},{"nameIdentifier":"98","nameIdentifierScheme":"九工大研究者情報","nameIdentifierURI":"https://hyokadb02.jimu.kyutech.ac.jp/html/98_ja.html"}],"names":[{"name":"Ohno, Teruhisa","nameLang":"en"},{"name":"横野, 照尚","nameLang":"ja"},{"name":"オウノ, テルヒサ","nameLang":"ja-Kana"}]}]},"item_21_link_62":{"attribute_name":"研究者情報","attribute_value_mlt":[{"subitem_link_url":"https://hyokadb02.jimu.kyutech.ac.jp/html/98_ja.html"}]},"item_21_publisher_7":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Nature Portfolio"}]},"item_21_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1038/s41929-021-00605-1","subitem_relation_type_select":"DOI"}}]},"item_21_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Nature portfolio"}]},"item_21_select_59":{"attribute_name":"査読の有無","attribute_value_mlt":[{"subitem_select_item":"yes"}]},"item_21_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"2520-1158","subitem_source_identifier_type":"ISSN"}]},"item_21_subject_16":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"431","subitem_subject_scheme":"NDC"}]},"item_21_text_28":{"attribute_name":"論文ID（連携）","attribute_value_mlt":[{"subitem_text_value":"10367938"}]},"item_21_text_36":{"attribute_name":"著者所属","attribute_value_mlt":[{"subitem_text_value":"Kyushu Institute of Technology, Joint Laboratory of Yangzhou University, Kyushu Institute of Technology"},{"subitem_text_value":"Shenzhen University"},{"subitem_text_value":"Nanyang Technological University"},{"subitem_text_value":"Toyota Technological Institute"},{"subitem_text_value":"Shenzhen University"},{"subitem_text_value":"National Synchrotron Radiation Research Center"},{"subitem_text_value":"Yangzhou University, Joint Laboratory of Yangzhou University, Kyushu Institute of Technology"},{"subitem_text_value":"Yangzhou University, Joint Laboratory of Yangzhou University, Kyushu Institute of Technology"},{"subitem_text_value":"Toyota Technological Institute"},{"subitem_text_value":"Shenzhen University"},{"subitem_text_value":"Nanyang Technological University"},{"subitem_text_value":"Kyushu Institute of Technology, Joint Laboratory of Yangzhou University, Kyushu Institute of Technology"}]},"item_21_text_63":{"attribute_name":"連携ID","attribute_value_mlt":[{"subitem_text_value":"9030"}]},"item_21_version_type_58":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Teng,  Zhenyuan"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Zhang,  Qitao"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yang,  Hongbin"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kato,  Kosaku"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yang,  Wenjuan"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Lu,  Ying-Rui"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Liu,  Sixiao"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Wang,  Chengyin"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yamakata,  Akira"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Su,  Chenliang"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Liu,  Bin"}],"nameIdentifiers":[{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"Ohno, Teruhisa","creatorNameLang":"en"},{"creatorName":"横野, 照尚","creatorNameLang":"ja"},{"creatorName":"オウノ, テルヒサ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{},{},{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2021-11-22"}],"displaytype":"detail","filename":"10367938.pdf","filesize":[{"value":"6.5 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"10367938.pdf","url":"https://kyutech.repo.nii.ac.jp/record/7358/files/10367938.pdf"},"version_id":"80beb634-a610-43c4-8cd8-bd263db0ef31"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Catalyst synthesis","subitem_subject_scheme":"Other"},{"subitem_subject":"Catalytic mechanisms","subitem_subject_scheme":"Other"},{"subitem_subject":"Energy","subitem_subject_scheme":"Other"},{"subitem_subject":"Heterogeneous catalysis","subitem_subject_scheme":"Other"},{"subitem_subject":"Photocatalysis","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Atomically dispersed antimony on carbon nitride for the artificial photosynthesis of hydrogen peroxide","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Atomically dispersed antimony on carbon nitride for the artificial photosynthesis of hydrogen peroxide"}]},"item_type_id":"21","owner":"3","path":["9"],"pubdate":{"attribute_name":"公開日","attribute_value":"2021-11-22"},"publish_date":"2021-11-22","publish_status":"0","recid":"7358","relation_version_is_last":true,"title":["Atomically dispersed antimony on carbon nitride for the artificial photosynthesis of hydrogen peroxide"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2024-04-02T08:36:34.651680+00:00"}