WEKO3
アイテム
ナノ構造を有する負極材料の開発と高性能リチウムイオン及びナトリウムイオン電池への応用
https://doi.org/10.18997/00008670
https://doi.org/10.18997/00008670ea4d8b2c-4a45-4950-a564-5926d620d387
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
sei_k_412.pdf (5.1 MB)
|
|
| Item type | 学位論文 = Thesis or Dissertation(1) | |||||||
|---|---|---|---|---|---|---|---|---|
| 公開日 | 2022-01-04 | |||||||
| 資源タイプ | ||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_db06 | |||||||
| 資源タイプ | doctoral thesis | |||||||
| タイトル | ||||||||
| タイトル | Development of Nanostructured Anode Materials and Application to High Performance Lithium-ion Batteries and Sodium-ion Batteries | |||||||
| 言語 | en | |||||||
| タイトル | ||||||||
| タイトル | ナノ構造を有する負極材料の開発と高性能リチウムイオン及びナトリウムイオン電池への応用 | |||||||
| 言語 | ja | |||||||
| 言語 | ||||||||
| 言語 | eng | |||||||
| 著者 |
Chen, Yun
× Chen, Yun
|
|||||||
| 抄録 | ||||||||
| 内容記述タイプ | Abstract | |||||||
| 内容記述 | The main research of this thesis focuses on improving specific capacity and stability by design and synthesis silicon-based anode composite materials to develop high performance lithium-ion batteries （LIB）. Firstly, we have synthesized a highly porous composite of SiOx/C by a simple in-situ synthesis method from an abundance carbon source, which was derived from equisetum arvense in nature. The obtained SiOx/C composite exhibits high capacities （773 mA h g−1 at 0.1 A g−1） as the anode materials of LIB after 100 cycles. To reduce the cost of LIB and replace Li, the sodium ion battery has been paid much attention. Therefore, we also synthesized a unique ternary hybrid structure by simultaneously growing nanoparticles of SnS2 and FeS2 on graphene sheet （SnS2 /FeS2 /rGO） via a simple hydrothermal method. We found that the SnS2 /FeS2 /rGO composite has high capacity （763.4 mA h g-1 at 0.1 A g−1） and show superior cycling stability than the pure materials of SnS2 and FeS2, respectively. These results show that design of the composite of bimetallic sulfide and graphene is an effect method to improve the performance for sodium ion batteries. In Chapter 1, we have introduced the background and the structure of lithium-ion batteries （LIBs） and sodium-ion batteries （SIBs）. In addition, we summarize the morphology and pore structure of biomass-derived materials and discuss the electrochemical performance of the LIBs and SIBs. In Chapter 2, we have obtained a highly porous composite of SiOx/C by a very simple in-situ synthesis method, which was derived from equisetum arvense. The derived SiOx/C anodes had an electrochemical performance with a large discharge capacity of 2366 mA h g−1 at 0.1 A g−1 in the first cycle and an appropriate reversible capacity of 773 mA h g−1 at 0.1 A g−1 after 100 cycles. In Chapter 3, we used rGO as a basement and synthesized SnS2/FeS2/rGO anode material through the hydrothermal method. Compared with the mono mental sulfide SnS2 and FeS2 anode material, the bimetal sulfide anode material SnS2/FeS2 /rGO has stronger conductivity and structural stability. When used for SIBs anode materials, it delivers a capacity of 763.4 mA h g-1 at the current density of 0.1 A g−1 after 100 cycles. In Chapter 4, in this work, we synthesized SnS2/C and FeS2/C composites which used crab shell as biomass carbon precursor. When used for sodium-ion batteries, SnS2/C and FeS2/C deliver a capacity of 535.4 and 479 mA h g-1 at the current density of 0.1A g-1, respectively. Final, the general conclusion is described. In this thesis, the as-prepared 4 kinds of materials exhibited good electrochemical performance in LIBs and SIBs. The strategies of combined SiOx/TMDS and biomass-based carbon providing a better solution for industrialization. | |||||||
| 目次 | ||||||||
| 内容記述タイプ | TableOfContents | |||||||
| 内容記述 | 1. Introduction ||2 Equisetum arvense derived anode material for lithium-ion batteries||3 Metallic Sulfide SnS2/FeS2 Nanosheets as High-Performance Anode Materials for Sodium-Ion Batteries||4 Carb shell-derived SnS2/C and FeS2/C carbon as anode for high-performance Sodium ion batteries | |||||||
| 備考 | ||||||||
| 内容記述タイプ | Other | |||||||
| 内容記述 | 九州工業大学博士学位論文 学位記番号：生工博甲第412号 学位授与年月日：令和3年9月24日 | |||||||
| キーワード | ||||||||
| 主題Scheme | Other | |||||||
| 主題 | Anode material | |||||||
| キーワード | ||||||||
| 主題Scheme | Other | |||||||
| 主題 | Lithium-ion batteries | |||||||
| キーワード | ||||||||
| 主題Scheme | Other | |||||||
| 主題 | Sodium-ion Batteries | |||||||
| キーワード | ||||||||
| 主題Scheme | Other | |||||||
| 主題 | Stability | |||||||
| キーワード | ||||||||
| 主題Scheme | Other | |||||||
| 主題 | Nanostructured | |||||||
| アドバイザー | ||||||||
| 馬, 廷麗 | ||||||||
| 学位授与番号 | ||||||||
| 学位授与番号 | 甲第412号 | |||||||
| 学位名 | ||||||||
| 学位名 | 博士（工学） | |||||||
| 学位授与年月日 | ||||||||
| 学位授与年月日 | 2021-09-24 | |||||||
| 学位授与機関 | ||||||||
| 学位授与機関識別子Scheme | kakenhi | |||||||
| 学位授与機関識別子 | 17104 | |||||||
| 学位授与機関名 | 九州工業大学 | |||||||
| 学位授与年度 | ||||||||
| 内容記述タイプ | Other | |||||||
| 内容記述 | 令和3年度 | |||||||
| 出版タイプ | ||||||||
| 出版タイプ | VoR | |||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||
| アクセス権 | ||||||||
| アクセス権 | open access | |||||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||||
| ID登録 | ||||||||
| ID登録 | 10.18997/00008670 | |||||||
| ID登録タイプ | JaLC | |||||||
