{"created":"2023-05-15T12:00:43.921826+00:00","id":7658,"links":{},"metadata":{"_buckets":{"deposit":"cea36453-8dc2-4652-85c6-040d8e2bceea"},"_deposit":{"created_by":3,"id":"7658","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"7658"},"status":"published"},"_oai":{"id":"oai:kyutech.repo.nii.ac.jp:00007658","sets":["8:9"]},"author_link":["33203","33197","33202","33195","33198","33196","33200","33204","33205","6794","33206","33207","33199"],"item_21_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020-05-25","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"118917","bibliographicVolumeNumber":"271","bibliographic_titles":[{"bibliographic_title":"Applied Catalysis B: Environmental"}]}]},"item_21_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Photocatalytic production of H2O2 from water and oxygen utilizing polymetric carbon nitride (PCN) is a promising alternative to the energy-consuming anthraquinone method. However, insufficient oxidation potential and limited light-absorption have restricted its further improvement. Herein, PCN with sufficient oxidation potential and improved visible-light usage (up to 550 nm) was prepared by co-polymerization of 2,5,8-triamino-tri-s-triazine (melem) and barbituric acid (BA). With the loading of Na2CoP2O7 as a water-oxidation co-catalyst, this novel PCN system showed a record-high apparent quantum efficiency (420 nm) of 8.0 % and a solar-to-chemical conversion efficiency of 0.30 % for H2O2 production. This improvement is attributed to the introduced O 2p states by CO groups remained in the PCN matrix, leading to a positive valence band maximum of 1.85 eV (vs. SHE). The co-polymerization of BA and melem combined with Na2CoP2O7 loading also suppressed the charge recombination, resulting in a rapid stepwise one-electron to one-electron reaction for efficient H2O2 production.","subitem_description_type":"Abstract"}]},"item_21_description_60":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"Journal Article","subitem_description_type":"Other"}]},"item_21_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"33202","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Teng,  Z."}]},{"nameIdentifiers":[{"nameIdentifier":"33203","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Cai,  W."}]},{"nameIdentifiers":[{"nameIdentifier":"33204","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Liu,  S."}]},{"nameIdentifiers":[{"nameIdentifier":"33205","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Wang,  C."}]},{"nameIdentifiers":[{"nameIdentifier":"33206","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Zhang,  Q."}]},{"nameIdentifiers":[{"nameIdentifier":"33207","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Chenliang,  S."}]},{"affiliations":[{"affiliationNames":[{"affiliationName":"","lang":"ja"}],"nameIdentifiers":[]}],"familyNames":[{"familyName":"Ohno","familyNameLang":"en"},{"familyName":"横野","familyNameLang":"ja"},{"familyName":"オウノ","familyNameLang":"ja-Kana"}],"givenNames":[{"givenName":"Teruhisa","givenNameLang":"en"},{"givenName":"照尚","givenNameLang":"ja"},{"givenName":"テルヒサ","givenNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"6794","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"10203887","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://nrid.nii.ac.jp/ja/nrid/1000010203887"},{"nameIdentifier":"7402659316","nameIdentifierScheme":"Scopus著者ID","nameIdentifierURI":"https://www.scopus.com/authid/detail.uri?authorId=7402659316"},{"nameIdentifier":"0000-0002-7825-8189","nameIdentifierScheme":"ORCiD","nameIdentifierURI":"https://orcid.org/0000-0002-7825-8189"},{"nameIdentifier":"98","nameIdentifierScheme":"九工大研究者情報","nameIdentifierURI":"https://hyokadb02.jimu.kyutech.ac.jp/html/98_ja.html"}],"names":[{"name":"Ohno, Teruhisa","nameLang":"en"},{"name":"横野, 照尚","nameLang":"ja"},{"name":"オウノ, テルヒサ","nameLang":"ja-Kana"}]}]},"item_21_link_62":{"attribute_name":"研究者情報","attribute_value_mlt":[{"subitem_link_url":"https://hyokadb02.jimu.kyutech.ac.jp/html/98_ja.html"}]},"item_21_publisher_7":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier"}]},"item_21_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1016/j.apcatb.2020.118917","subitem_relation_type_select":"DOI"}}]},"item_21_rights_13":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright (c) 2020 Elsevier B.V. All rights reserved."}]},"item_21_select_59":{"attribute_name":"査読の有無","attribute_value_mlt":[{"subitem_select_item":"yes"}]},"item_21_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0926-3373","subitem_source_identifier_type":"ISSN"}]},"item_21_subject_16":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"431","subitem_subject_scheme":"NDC"}]},"item_21_text_28":{"attribute_name":"論文ID（連携）","attribute_value_mlt":[{"subitem_text_value":"10358098"}]},"item_21_text_36":{"attribute_name":"著者所属","attribute_value_mlt":[{"subitem_text_value":"Kyushu Institute of Technology, Joint Laboratory of Yangzhou University, Kyushu Institute of Technology"},{"subitem_text_value":"Kyushu Institute of Technology"},{"subitem_text_value":"Yangzhou University, Joint Laboratory of Yangzhou University, Kyushu Institute of Technology"},{"subitem_text_value":"Yangzhou University, Joint Laboratory of Yangzhou University, Kyushu Institute of Technology"},{"subitem_text_value":"Shenzhen University"},{"subitem_text_value":"Shenzhen University"},{"subitem_text_value":"Kyushu Institute of Technology, Joint Laboratory of Yangzhou University, Kyushu Institute of Technology"}]},"item_21_text_63":{"attribute_name":"連携ID","attribute_value_mlt":[{"subitem_text_value":"8347"}]},"item_21_version_type_58":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Teng,  Zhenyuan"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Cai,  Wenan"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Liu,  Sixiao"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Wang,  Chengyin"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Zhang,  Qitao"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Su,  Chenliang"}],"nameIdentifiers":[{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"Ohno, Teruhisa","creatorNameLang":"en"},{"creatorName":"横野, 照尚","creatorNameLang":"ja"},{"creatorName":"オウノ, テルヒサ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{},{},{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2022-05-25"}],"displaytype":"detail","filename":"iENERON-2020_09.pdf","filesize":[{"value":"1.8 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"iENERON-2020_09.pdf","url":"https://kyutech.repo.nii.ac.jp/record/7658/files/iENERON-2020_09.pdf"},"version_id":"47513541-bc37-49d7-a3fb-8a09dd4159ac"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Photocatalysis","subitem_subject_scheme":"Other"},{"subitem_subject":"Nonsacrificial H2O2production","subitem_subject_scheme":"Other"},{"subitem_subject":"Band engineering","subitem_subject_scheme":"Other"},{"subitem_subject":"Carbon nitride","subitem_subject_scheme":"Other"},{"subitem_subject":"Polymer design and synthesis","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Bandgap engineering of polymetric carbon nitride copolymerized by 2,5,8-triamino-tri-s-triazine (melem) and barbituric acid for efficient nonsacrificial photocatalytic H2O2 production","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Bandgap engineering of polymetric carbon nitride copolymerized by 2,5,8-triamino-tri-s-triazine (melem) and barbituric acid for efficient nonsacrificial photocatalytic H2O2 production"}]},"item_type_id":"21","owner":"3","path":["9"],"pubdate":{"attribute_name":"公開日","attribute_value":"2022-05-25"},"publish_date":"2022-05-25","publish_status":"0","recid":"7658","relation_version_is_last":true,"title":["Bandgap engineering of polymetric carbon nitride copolymerized by 2,5,8-triamino-tri-s-triazine (melem) and barbituric acid for efficient nonsacrificial photocatalytic H2O2 production"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2024-04-02T08:41:10.025841+00:00"}