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Simple Procedure for Polystyrene-based Nanocomposite Preparation by Vapor-Phase Assisted Surface Polymerization
http://hdl.handle.net/10228/00006738
http://hdl.handle.net/10228/000067389e17c380-0a94-427c-9429-8651b2f2eb23
名前 / ファイル | ライセンス | アクション |
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10219050.pdf (2.1 MB)
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Item type | 学術雑誌論文 = Journal Article(1) | |||||||||||||||||
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公開日 | 2018-05-08 | |||||||||||||||||
資源タイプ | ||||||||||||||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||||||||
資源タイプ | journal article | |||||||||||||||||
タイトル | ||||||||||||||||||
言語 | en | |||||||||||||||||
タイトル | Simple Procedure for Polystyrene-based Nanocomposite Preparation by Vapor-Phase Assisted Surface Polymerization | |||||||||||||||||
言語 | ||||||||||||||||||
言語 | eng | |||||||||||||||||
著者 |
安藤, 義人
× 安藤, 義人
WEKO
21654
× Jeong, Jae-Mun× 西田, 治男
WEKO
21961
× 遠藤, 剛 |
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抄録 | ||||||||||||||||||
内容記述タイプ | Abstract | |||||||||||||||||
内容記述 | Polystyrene (PSt)-based copolymer/montmorillonite (MMT) nanocomposites were prepared by an in-situ vapor-phase assisted surface polymerization (VASP) as a solventless method using an organically modified MMT and a free radical initiator. Simultaneous and consecutive VASP of styrene (St) and methyl methacrylate (MMA) on the pre-modified MMT induced the accumulation of poly(MMA-ran-St) and poly(MMA-block-St) on the MMT surface, resulting in effective intercalation and exfoliation of silicate layers. The homogeneously dispersed silicate platelets in the polymer matrices were confirmed by X-ray diffraction and transmission electron microscope analyses. An important contributor to this phenomenon must be the particular interaction between a small amount of MMA-units and silicate surfaces. This approach allows the nanocomposites with accompanying intercalation and exfoliation of silicate layers to be applied to a wide range of vaporizable monomers which in the absence of this technique would be otherwise difficult to individually prepare. | |||||||||||||||||
言語 | en | |||||||||||||||||
書誌情報 |
en : Macromolecules 巻 42, 号 20, p. 7930-7935, 発行日 2009-09-16 |
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出版社 | ||||||||||||||||||
言語 | en | |||||||||||||||||
出版者 | American Chemical Society | |||||||||||||||||
DOI | ||||||||||||||||||
関連タイプ | isVersionOf | |||||||||||||||||
識別子タイプ | DOI | |||||||||||||||||
関連識別子 | https://doi.org/10.1021/ma901357p | |||||||||||||||||
NCID | ||||||||||||||||||
収録物識別子タイプ | NCID | |||||||||||||||||
収録物識別子 | AA0071963X | |||||||||||||||||
ISSN | ||||||||||||||||||
収録物識別子タイプ | EISSN | |||||||||||||||||
収録物識別子 | 1520-5835 | |||||||||||||||||
ISSN | ||||||||||||||||||
収録物識別子タイプ | PISSN | |||||||||||||||||
収録物識別子 | 0024-9297 | |||||||||||||||||
著作権関連情報 | ||||||||||||||||||
権利情報 | Copyright (c) 2009 American Chemical Society | |||||||||||||||||
キーワード | ||||||||||||||||||
主題Scheme | Other | |||||||||||||||||
主題 | exfoliation | |||||||||||||||||
キーワード | ||||||||||||||||||
主題Scheme | Other | |||||||||||||||||
主題 | nanocomposite | |||||||||||||||||
キーワード | ||||||||||||||||||
主題Scheme | Other | |||||||||||||||||
主題 | organoclay | |||||||||||||||||
キーワード | ||||||||||||||||||
主題Scheme | Other | |||||||||||||||||
主題 | radical polymerization | |||||||||||||||||
キーワード | ||||||||||||||||||
主題Scheme | Other | |||||||||||||||||
主題 | vapor-phase assisted surface polymerization | |||||||||||||||||
出版タイプ | ||||||||||||||||||
出版タイプ | AM | |||||||||||||||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||||||||||||||
査読の有無 | ||||||||||||||||||
値 | yes | |||||||||||||||||
研究者情報 | ||||||||||||||||||
https://hyokadb02.jimu.kyutech.ac.jp/html/397_ja.html | ||||||||||||||||||
論文ID(連携) | ||||||||||||||||||
10219050 | ||||||||||||||||||
連携ID | ||||||||||||||||||
6964 |