| アイテムタイプ |
学術雑誌論文 = Journal Article(1) |
| 公開日 |
2024-01-09 |
| 資源タイプ |
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|
資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
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資源タイプ |
journal article |
| タイトル |
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|
タイトル |
Intercalation on Transition Metal Trichalcogenides via a Quasi‐Amorphous Phase with 1D Order |
|
言語 |
en |
| その他のタイトル |
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|
その他のタイトル |
Intercalation on transition metal trichalcogenides via a quasi-amorphous phase with 1D order |
|
言語 |
en |
| 言語 |
|
|
言語 |
eng |
| 著者 |
Fujioka, Masaya
Jeem, Melbert
Sato, Kento
田中, 将嗣
Morita, Kazuki
Shibuya, Taizo
Takahashi, Kiyonori
Iwasaki, Suguru
Miura, Akira
Nagao, Masanori
Demura, Satoshi
Sakata, Hideaki
Ono, Madoka
Kaiju, Hideo
Nishii, Junji
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| 抄録 |
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内容記述タイプ |
Abstract |
|
内容記述 |
Intercalation into 1D transition metal trichalcogenides (TMTs) in which fibers are bonded by a weak van der Waals force can be expected to create various intercalation compounds and develop unique physical properties according to the combination of the host materials and guest ions. However, structural changes via intercalation into 1D TMTs are not as simple as those in 2D transition metal dichalcogenides (TMDs) and are still not understood comprehensively. ZrTe3: a typical compound with a 1D trigonal prismatic structure, belongs to TMTs. Herein, through the Ag introduction to ZrTe3 via solid-state intercalation, a novel crystal phase with a 1D octahedral structure and a quasi-amorphous (QA) phase during the structural transition are discovered; the QA phase is a novel state of matter in which long-range order is lost while retaining 1D order. Based on the Ag concentration, the transport properties are flexibly modulated from superconductivity to semiconductivity. Density functional theory calculations indicate the attraction between Ag ions and the pair diffusion due to their attraction. Furthermore, judging the attraction or repulsion between guest ions predicts whether to induce a QA phase or simple lattice expansion like the intercalation into 2D TMDs. |
|
言語 |
en |
| 書誌情報 |
en : Advanced Functional Materials
巻 33,
号 10,
p. 2208702,
発行日 2023-01-07
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| 出版社 |
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出版者 |
Wiley |
| DOI |
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関連タイプ |
isVersionOf |
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|
識別子タイプ |
DOI |
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|
関連識別子 |
https://doi.org/10.1002/adfm.202208702 |
| ISSN |
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収録物識別子タイプ |
EISSN |
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収録物識別子 |
1616-3028 |
| ISSN |
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収録物識別子タイプ |
PISSN |
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収録物識別子 |
1616-301X |
| 著作権関連情報 |
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|
権利情報 |
Copyright (c) 2023 Wiley-VCH GmbH |
| 出版タイプ |
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出版タイプ |
AM |
|
出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
| 査読の有無 |
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|
値 |
yes |
| 研究者情報 |
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|
URL |
https://hyokadb02.jimu.kyutech.ac.jp/html/100001006_ja.html |
| 論文ID（連携） |
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|
値 |
10406171 |
| 連携ID |
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|
値 |
11079 |
adfm.202208702.pdf (6.1 MB)
