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Controlling the TiO2–Dye Nanomolecular Interactions for Improving the Photoconversion in Transparent Dye‐Sensitized Solar Cells
http://hdl.handle.net/10228/0002000768
http://hdl.handle.net/10228/0002000768d675badd-b339-41c5-b559-eb52afb943a2
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10430686.pdf (570 KB)
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Item type | 学術雑誌論文 = Journal Article(1) | |||||||||||
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公開日 | 2024-06-13 | |||||||||||
資源タイプ | ||||||||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||
資源タイプ | journal article | |||||||||||
タイトル | ||||||||||||
タイトル | Controlling the TiO2–Dye Nanomolecular Interactions for Improving the Photoconversion in Transparent Dye‐Sensitized Solar Cells | |||||||||||
言語 | en | |||||||||||
その他のタイトル | ||||||||||||
その他のタイトル | Controlling the TiO 2 –Dye Nanomolecular Interactions for Improving the Photoconversion in Transparent Dye‐Sensitized Solar Cells | |||||||||||
言語 | en | |||||||||||
言語 | ||||||||||||
言語 | eng | |||||||||||
著者 |
Roy, Pritha
× Roy, Pritha
× Kurokawa, Yuki
× Pandey, Shyam S.
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抄録 | ||||||||||||
内容記述タイプ | Abstract | |||||||||||
内容記述 | Herein, transparent dye-sensitized solar cells (DSSCs) are fabricated using two sensitizing dyes aiming toward panchromatic photon harvesting following two different approaches of dye adsorption such as using dye cocktail and sequential dye adsorption. A combination of complementary yellow-colored dye (D-131) and green-colored far-red-sensitive squaraine dye (SQ-140) is judiciously selected not only for panchromatic light absorption but also for bypassing the absorption in the high eye-sensitivity wavelength region (500–600 nm) region to improve the transparency. The DSSC fabricated using a dye cocktail of D-131 and SQ-140 in a 9:1 molar ratio exhibits a photoconversion efficiency (PCE) and average visible transparency (AVT) of 3.89% and 36.9%, respectively. In contrast, stepwise and controlled dye adsorption of SQ-140 followed by D-131 on mesoporous TiO2 leads to further improvement in the PCE from 3.89% to 4.50%, while AVT is reduced from 36.9% to 15.6%. This marked improvement in the PCE for the stepwise co-sensitized transparent DSSCs is attributed to the suppression of unfavorable inter-dye interaction leading to synergistic photon harvesting by both of the constituent sensitizing dyes. | |||||||||||
言語 | en | |||||||||||
書誌情報 |
en : Physica Status Solidi. A, Applications and Materials Science 巻 220, 号 24, p. 2300158, 発行日 2023-06-28 |
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出版者 | Wiley | |||||||||||
DOI | ||||||||||||
識別子タイプ | DOI | |||||||||||
関連識別子 | https://doi.org/10.1002/pssa.202300158 | |||||||||||
NCID | ||||||||||||
収録物識別子タイプ | NCID | |||||||||||
収録物識別子 | AA12238581 | |||||||||||
ISSN | ||||||||||||
収録物識別子タイプ | PISSN | |||||||||||
収録物識別子 | 1862-6300 | |||||||||||
ISSN | ||||||||||||
収録物識別子タイプ | EISSN | |||||||||||
収録物識別子 | 1862-6319 | |||||||||||
著作権関連情報 | ||||||||||||
権利情報 | Copyright (c) 2023 Wiley-VCH GmbH | |||||||||||
キーワード | ||||||||||||
主題Scheme | Other | |||||||||||
主題 | Transparent DSSCs | |||||||||||
キーワード | ||||||||||||
主題Scheme | Other | |||||||||||
主題 | Inter-dye interaction | |||||||||||
キーワード | ||||||||||||
主題Scheme | Other | |||||||||||
主題 | Dye-cocktail | |||||||||||
キーワード | ||||||||||||
主題Scheme | Other | |||||||||||
主題 | Stepwise dye adsorption | |||||||||||
キーワード | ||||||||||||
主題Scheme | Other | |||||||||||
主題 | Far-red dye | |||||||||||
出版タイプ | ||||||||||||
出版タイプ | AM | |||||||||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||||||||
査読の有無 | ||||||||||||
値 | yes | |||||||||||
研究者情報 | ||||||||||||
URL | https://hyokadb02.jimu.kyutech.ac.jp/html/332_ja.html | |||||||||||
論文ID(連携) | ||||||||||||
値 | 10430686 | |||||||||||
連携ID | ||||||||||||
値 | 12309 |