WEKO3
アイテム
Macroscopic self ordering of solution processible poly (3,3'-dialkylquaterthiophene) by floating film transfer method
http://hdl.handle.net/10228/5910
http://hdl.handle.net/10228/59106a626c7a-ea56-4b81-9f75-5ca6edab95af
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
JAP114_054309.pdf (2.2 MB)
|
|
| Item type | 学術雑誌論文 = Journal Article(1) | |||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 公開日 | 2016-11-22 | |||||||||||||
| 資源タイプ | ||||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||||
| 資源タイプ | journal article | |||||||||||||
| タイトル | ||||||||||||||
| タイトル | Macroscopic self ordering of solution processible poly (3,3'-dialkylquaterthiophene) by floating film transfer method | |||||||||||||
| 言語 | ||||||||||||||
| 言語 | eng | |||||||||||||
| 著者 |
Pandey, Rajiv K
× Pandey, Rajiv K× 高嶋, 授× 永松, 秀一
WEKO
1670
× Dauendorffer, Arnaud× Kaneto, K× Prakash, Rajiv |
|||||||||||||
| 抄録 | ||||||||||||||
| 内容記述タイプ | Abstract | |||||||||||||
| 内容記述 | Ordering and alignment of p-conjugated polymer chains are highly desirable for high performance and long life organic electronic devices. We report here self assembly of ordered and aligned solution processible Poly(3,3‴-dialkylquaterthiophene) (PQT-12) polymer at macroscopic level using Floating Film Transfer Method (FTM). PQT-12 polymer film is formed over solution of ethylene glycol and glycerol at different temperatures viz. 22, 26, 33, and 38 C. PQT-12 films formed by FTM technique are further characterized for optical and morphological properties. UV-vis absorption (for polarize and unpolarize light) and surface topography/phase imaging are carried out by using UV-vis spectrometer and atomic force microscope (AFM), respectively. UV-vis spectra show the polymer chains alignment perpendicular to the film propagation direction and it is well supported by AFM images. The effect of temperature on ordering and alignment of PQT-12 shows 33 C as an optimum temperature for alignment of polymer chains (a little compromise in ordering). The heating of polymer films at 110 C for 2 h in ambient causes significant changes in UV-vis absorbance spectra, optical anisotropy, and AFM topography/phase imaging. Our studies provide better understanding of ordering and alignment of PQT-12 chains and also disordering on heating. This work further provides a facile and user-friendly technique for the long range ordered self assembly of PQT-12, which shows enormous potential for various electronic applications. | |||||||||||||
| 書誌情報 |
Journal of Applied Physics 巻 114, 号 5, p. 054309-1-054309-8, 発行日 2013-08-05 |
|||||||||||||
| 出版社 | ||||||||||||||
| 出版者 | American Institute of Physics | |||||||||||||
| DOI | ||||||||||||||
| 関連タイプ | isIdenticalTo | |||||||||||||
| 識別子タイプ | DOI | |||||||||||||
| 関連識別子 | info:doi/10.1063/1.4817288 | |||||||||||||
| NCID | ||||||||||||||
| 収録物識別子タイプ | NCID | |||||||||||||
| 収録物識別子 | AA00693547 | |||||||||||||
| ISSN | ||||||||||||||
| 収録物識別子タイプ | ISSN | |||||||||||||
| 収録物識別子 | 0021-8979 | |||||||||||||
| ISSN | ||||||||||||||
| 収録物識別子タイプ | ISSN | |||||||||||||
| 収録物識別子 | 1089-7550 | |||||||||||||
| 出版タイプ | ||||||||||||||
| 出版タイプ | VoR | |||||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||||||
| 査読の有無 | ||||||||||||||
| 値 | yes | |||||||||||||
| 研究者情報 | ||||||||||||||
| URL | https://hyokadb02.jimu.kyutech.ac.jp/html/217_ja.html | |||||||||||||
| 連携ID | ||||||||||||||
| 値 | 5823 | |||||||||||||
| 情報源 | ||||||||||||||
| 識別子タイプ | URI | |||||||||||||
| 関連識別子 | http://scitation.aip.org/content/aip/journal/jap | |||||||||||||
| 関連名称 | http://scitation.aip.org/content/aip/journal/jap | |||||||||||||
