WEKO3
アイテム
Photocatalytic Synthesis of p-Anisaldehyde in a Mini Slurry-Bubble Reactor under Solar Light Irradiation
http://hdl.handle.net/10228/00007853
http://hdl.handle.net/10228/000078539a181eca-2bf8-44f0-a6e0-4e18c6f8b2e9
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
iENERON-2020_13.pdf (424.0 kB)
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| アイテムタイプ | 学術雑誌論文 = Journal Article(1) | |||||||||||||
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| 公開日 | 2020-08-18 | |||||||||||||
| 資源タイプ | ||||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||||
| 資源タイプ | journal article | |||||||||||||
| タイトル | ||||||||||||||
| タイトル | Photocatalytic Synthesis of p-Anisaldehyde in a Mini Slurry-Bubble Reactor under Solar Light Irradiation | |||||||||||||
| 言語 | en | |||||||||||||
| その他のタイトル | ||||||||||||||
| その他のタイトル | Photocatalytic Synthesis of p‐Anisaldehyde in a Mini Slurry‐Bubble Reactor under Solar Light Irradiation | |||||||||||||
| 言語 | en | |||||||||||||
| 言語 | ||||||||||||||
| 言語 | eng | |||||||||||||
| 著者 |
Heggo, Dalia
× Heggo, Dalia× Ookawara, Shinichi× 横野, 照尚
WEKO
6794
× Nakai, Toru× Matsushita, Yoshihisa× Eldin, Gamal Mona× Ohshima, Masahiro |
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| 抄録 | ||||||||||||||
| 内容記述タイプ | Abstract | |||||||||||||
| 内容記述 | Dense photocatalyst slurry was employed for the synthesis of p‐anisaldehyde under solar light irradiation. An Fe‐modified rutile TiO 2 (Fe‐TiO 2, 34.5 m 2/g) photocatalyst was used as a visible‐light‐responsive photocatalyst. A conventional TiO 2 (P25, 35 m 2/g) photocatalyst was also examined as a reference catalyst. XRD patterns and diffuse reflectance spectra showed that Fe‐TiO 2 consists of 100 % rutile phase and absorbs more visible light compared to P25, respectively. The catalyst powder was suspended in an ethyl acetate solution of p‐methoxytoluene in the mini‐reactor, with oxygen bubbling, under a solar simulator, visible light, and UV LEDs. p‐anisaldehyde, as a reaction product, was analyzed by sampling using gas‐chromatograph. Regardless of the light source, Fe‐TiO 2 always outperformed P25 in terms of both generation rates (GR) of p‐anisaldehyde and energy requirements (ER). It was demonstrated that the highly dense Fe‐TiO 2 slurry was efficient for the synthesis under solar light owing to the small size of the reactor. The small amount of Pt and ZrO 2 cocatalysts significantly enhanced the GR under solar light. By adopting a visible light responsive Fe‐TiO 2 photocatalyst, the mini slurry‐bubble reactor under solar light achieved a high GR per catalyst mass (CM), which is one to two orders higher than that reported by most previous studies with high‐power lamps. | |||||||||||||
| 言語 | en | |||||||||||||
| 書誌情報 |
en : The Canadian Journal of Chemical Engineering 巻 98, 号 1, p. 119-126, 発行日 2019-07-03 |
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| 出版社 | ||||||||||||||
| 出版者 | Wiley | |||||||||||||
| DOI | ||||||||||||||
| 関連タイプ | isVersionOf | |||||||||||||
| 識別子タイプ | DOI | |||||||||||||
| 関連識別子 | https://doi.org/10.1002/cjce.23586 | |||||||||||||
| 日本十進分類法 | ||||||||||||||
| 主題Scheme | NDC | |||||||||||||
| 主題 | 431 | |||||||||||||
| ISSN | ||||||||||||||
| 収録物識別子タイプ | PISSN | |||||||||||||
| 収録物識別子 | 0008-4034 | |||||||||||||
| ISSN | ||||||||||||||
| 収録物識別子タイプ | EISSN | |||||||||||||
| 収録物識別子 | 1939-019X | |||||||||||||
| 著作権関連情報 | ||||||||||||||
| 権利情報 | Copyright (c) 2019 Canadian Society for Chemical Engineering | |||||||||||||
| キーワード | ||||||||||||||
| 主題Scheme | Other | |||||||||||||
| 主題 | photocatalysis | |||||||||||||
| キーワード | ||||||||||||||
| 主題Scheme | Other | |||||||||||||
| 主題 | solar light | |||||||||||||
| キーワード | ||||||||||||||
| 主題Scheme | Other | |||||||||||||
| 主題 | organic synthesis | |||||||||||||
| キーワード | ||||||||||||||
| 主題Scheme | Other | |||||||||||||
| 主題 | titanium dioxide | |||||||||||||
| キーワード | ||||||||||||||
| 主題Scheme | Other | |||||||||||||
| 主題 | mini reactor | |||||||||||||
| 出版タイプ | ||||||||||||||
| 出版タイプ | AM | |||||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||||||||||
| 査読の有無 | ||||||||||||||
| 値 | yes | |||||||||||||
| 研究者情報 | ||||||||||||||
| URL | https://hyokadb02.jimu.kyutech.ac.jp/html/98_ja.html | |||||||||||||
| 論文ID（連携） | ||||||||||||||
| 値 | 10358770 | |||||||||||||
| 連携ID | ||||||||||||||
| 値 | 8378 | |||||||||||||
